Calculation of Electrochemical Parameters Starting from the Polarization Curves of Ferrocene at Glassy Carbon Electrode

Neghmouche, N.S.; Lanez, Touhami

doi:10.18052/www.scipress.com/ILCPA.9.37

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Calculation of Electrochemical Parameters Starting from the Polarization Curves of Ferrocene at Glassy Carbon Electrode

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Abstract:

This work is a contribution to the calculation of electrochemical parameters from the polarization curves of ferrocene. The parameters are: The anodic (E_pa) and the cathodic (E_pc) peak potentials, as well as the corresponding anodic (i_pa) and cathodic (i_pc) peak currents, were obtained at different scan rates (0.05, 0.10, 0.30, 0.50 V.s^-1). The half-wave potentials (E_1/2) of the couple in the investigated solvents have been evaluated. The diffusion coefficients (D) have been calculated using the Randles-Sevcik equation.

Info:

Periodical:

International Letters of Chemistry, Physics and Astronomy (Volume 9)

Pages:

37-45

DOI:

https://doi.org/10.18052/www.scipress.com/ILCPA.9.37

Citation:

N.S. Neghmouche and T. Lanez, "Calculation of Electrochemical Parameters Starting from the Polarization Curves of Ferrocene at Glassy Carbon Electrode", International Letters of Chemistry, Physics and Astronomy, Vol. 9, pp. 37-45, 2013

Online since:

March 2013

Authors:

N.S. Neghmouche, Touhami Lanez

Keywords:

Cyclic Voltammetry, Diffusion Coefficient, Ferrocene, Half-Wave Potential, Randles-Sevcik Equation

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Open Access

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Creative Commons Attribution 4.0 International License

References:

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