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ILCPA > Volume 8 > Synthesis and Spectral Studies of Ru(II) Carbonyl...
Synthesis and Spectral Studies of Ru(II) Carbonyl Schiff Base Complexes
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Synthesis and Spectral Studies of Ru(II) Carbonyl Schiff Base Complexes

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Abstract:

The synthesis and characterization of hexa co-ordinated ruthenium(II) complexes of the type [Ru(CO)(B)(L)] (where B = PPh3, AsPh3, py or pip and L = dibasic tetradentate Schiff base ligand) were synthesized from the reaction of [RuHCl(CO)(B)(EPh3)2] (where E = P, B = PPh3, py or pip, E = As, B = AsPh3) with different tetradentate ligands. The ligands were derived by the condensation of 5-chloro-4-methyl-2-hydroxy benzophenone with ethylenediamine, propylenediamine and o-phenylene-diamine in 1:1 molar ratio. All the compounds have been characterized by elemental analysis and spectral (FT-IR, UV-VIS and 1H-NMR) methods. An octahedral environment around Ru(II) ion has been tentatively proposed for all the complexes

Info:

Periodical:
International Letters of Chemistry, Physics and Astronomy (Volume 8)
Pages:
53-66
DOI:
https://doi.org/10.18052/www.scipress.com/ILCPA.8.53
Citation:
B. Prabhakaran et al., "Synthesis and Spectral Studies of Ru(II) Carbonyl Schiff Base Complexes", International Letters of Chemistry, Physics and Astronomy, Vol. 8, pp. 53-66, 2013
Online since:
September 2013
Authors:
B. Prabhakaran, N. Santhi, M. Emayavaramban
Keywords:
Octahedral Environment, Ruthenium(II) Complexes, Schiff Base, Tetradentate Ligands
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Distribution:
Open Access

Creative Commons License
This work is licensed under a
Creative Commons Attribution 4.0 International License

References:

[1] A. M. El-Hendawy, A. H. Alkubasi, A. El-Ghany, K. El-Kourashym, M. N. Sharab, Polyhedron 20 (2001) 975.

[2] P. K. Bhattacharya, Proc. Ind. Acad. Sci. (Chem. Sci. ) 102 (1990) 247.

[3] A. Bader, E. Linder, Coord. Chem. Rev. 27 (1991) 108.

[4] C. Slugove, P. Wiede, K. Mereiter, R. Schmid, K. Kirchner, Organometallics 16 (1997) 2768.

[5] F. Mevellec, S. Collet, D. Deniaud, A. Reliquet, J. Meslin, J. Chem. Soc. (2001) 3128.

[6] V. R. de Souza, G. S. Nunes, R. C. Rocha, H. E. Toma, Inorg. Chim. Acta. 348 (2003) 50.

[7] A. D. Garnovskii, A. L. Nivorozhkin, V. I. Minkin, Coord. Chem. Rev. 126 (1993).

[8] R. Ziessel, Coord. Chem. Rev. 195 (2001) 216.

[9] C. A. McAuliffe, W. Leavason, Phosphine, Arsine and Stilbine Complexes of the Transition Elements, Elseiver, Amsterdam, (1979).

[10] K. -I. Na, S. Huh, K. M. Sung, M. -Jun, Polyhedron 15 (1996) 1841.

[11] M. Ito, M. Hirakawa, K. Murata, T. Ikariya, Organometallics 20 (2001) 379.

[12] G. P. C. M. Dekker, A. Bujis, C. J. Elsevier, K. Vrieze, P. W. N. M. Van Leeuwen, W. J. J. Smeets, A. L. Spek, Y. F. Wang, C. H. Stam, Organometallics 11 (1992) (1937).

[13] A. Habtemariam, B. Watchman, B. S. Potter, R. Palmer, S. Parsons, A. Parkin, P. J. Sadler, J. Chem. Soc. Dalton Trans. (2001) 1306.

[14] A. Mansour, M. Portnoy, J. Chem. Soc. Perkin Trans. 1 (2001) 952.

[15] A. Das, S. -M. Peng, G. -H. Lee, S. Bhattacharya, New. J. Chem. 28 (2004) 712.

[16] L. N. Ji, X. -H. Zou, J. -G. Liu, Coord. Chem. Rev. 513 (2001) 216.

[17] S. I. Gorelsky, A. B. P. Lever, M. Ebadi, Coord. Chem. Rev. 97 (2002) 230.

[18] M. J. Clarke, Coord. Chem. Rev. 209 (2003) 236.

[19] B. Serli, E. Zangrrando, T. Gianferrara, L. Yellowless, E. Alessio, Coord. Chem. Rev. 73 (2003) 245.

[20] X. –G. Zhou, J. –S. Huang, P. –H. Ko, K. –K. Cheung, C. –M. Che, J. Chem. Soc. Dalton Trans. (1999) 3303.

[21] W. Ruttinger, G. C. Dismukes, Chem. Rev. 1 (1997) 97.

[22] W. Odenkirk, A. L. Rheingold, B. Bosnich, J. Am. Chem. Soc. 114 (1992) 6392.

[23] M. L. P. Santos, I. A. Bagatin, E. M. Pereira, A. M. C. Ferreira, J. Chem. Soc., Dalton Trans. (2001) 838.

[24] S. Menage, J. -B. Galey, J. Dumats, G. Hussler, M. Seite, J. Am. Chem. Soc. 120 (1998) 13370.

[25] J. -P. Costes, F. Dahan, A. Dupuis, J. -P. Laurent, J. Chem. Soc. Dalton Trans. (1998) 1307.

[26] E. -G. Jager, J. Knaudt, M. Rudolph, M. Rost, Chem. Ber. 129 (1996) 1041.

[27] S. R. Collinson, D. E. Fenton, Coord. Chem. Rev. 19 (1996) 148.

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