Subscribe

Subscribe to our Newsletter and get informed about new publication regulary and special discounts for subscribers!

ILCPA > Volume 67 > Kinetic Spectrophotometric Method for...
< Back to Volume

Kinetic Spectrophotometric Method for Determination of Vanadium in Syrian Oil Using 1,5-Diphenylcarbazide Reagent

Full Text PDF

Abstract:

New, sensitive, accurate and inexpensive kinetic spectrophotometric method was developed and validated for the determination of V(V) in crude oil and its heavy product. The method is based on the formation of colored complex between V(V) and 1, 5-diphenylcarbazide (DPCI). The method involves the reaction of V(V) with DPCI in presence of buffer solution of pH 6.8 to form colored complex with λmax at 530 nm. The fixed time method (2000 Sec) was adopted for constructing the calibration curve. The linearity range was found to be (2-12) mg/L. The correlation coefficient was 0.9999 and the limit of detection was found to be 0.349 mg/L. The method is feasible with the calibration equations obtained, which makes this method more applicable. Statistical treatment of the experimental results indicates that the method is precise, selective and accurate. The method was successfully applied for determination of V(V) in Syrian crude oil and its heavy product.

Info:

Periodical:
International Letters of Chemistry, Physics and Astronomy (Volume 67)
Pages:
42-49
Citation:
I. Moustafa et al., "Kinetic Spectrophotometric Method for Determination of Vanadium in Syrian Oil Using 1,5-Diphenylcarbazide Reagent", International Letters of Chemistry, Physics and Astronomy, Vol. 67, pp. 42-49, 2016
Online since:
Jun 2016
Export:
Distribution:
References:

[1] G. Goldstein, D.L. Manning, O. Menis, Spectrophotometric Methods for The Determination of Osmium-Ii, J. Talanta. 7 (1961) 301-306.

DOI: https://doi.org/10.1016/0039-9140(61)80024-6

[2] S. Jaya. Y, T.V. Ramakrishna, Spectrophotometric Determination of Osmium with 1, 5_Diphenylcarbazide, J. Talanta. 29 (1982) 619-622.

[3] A.R. Paniagua, M.D. Vazquez, M.L. Tascon, P.S. Batanero, Determination of Chromium(VI) and Chromium(III) by Using a Diphenylcarbazide-Modified Carbon Paste Electrode, J. Electro. Anal. 5 (1993) 155-163.

DOI: https://doi.org/10.1002/elan.1140050211

[4] L. Girard, J. Hubert, Speciation of Chromium (VI) and Total Chromium Determination in Welding Dust Samples by Flow-Injection Analysis Coupled to Atomic Absorption Spectrometry, J. Talanta. 43 (1996) 1965-(1974).

DOI: https://doi.org/10.1016/0039-9140(96)01985-6

[5] M.J. Ahmed, S. Banoo, Spectrophotometric Method for Determination of Vanadium and Its Application To Industrial, Environmental, Biological And Soil Samples, J. Talanta. 48 (1999) 1085-1094.

DOI: https://doi.org/10.1016/s0039-9140(98)00329-4

[6] P. Rana, R. Lokhande, S. Pitale, S. Janwadkar, D. Yadav, Spectrophotometric Determination of Vanadium with Acetophenone 2ˋ, 4ˋ-Dihydroxy Thiosemicarbazone, J. Chem. Tech. 6 (2014) 2295-2299.

[7] K. A. Kuliyev, N. A. Verdizade, Spectroscopic Investiqation Complex Formation of Vanadium Using 2, 6-Dithiolphenol and Hydrofob Amins, J. Amer. Chem. 5 (2015) 10-18.

[8] B.V.N. Reddy, V.S. Basha, T.S. Reddy, Determination of titanium and Vanadium with 2, 4-Dihydroxy acetophenone isonicotinoylhydrazone by Direct and Derivative Spectrophotometric Method, J. Der. Pharma. Chemica, 7 (2015) 16-25.

[9] P.G. Chowdary, V.S. Basha, Determination of Vanadium in Different Environmental, Leafy Vegetable and Biological Samples Using 2-hydroxy-1-naphthaldehyde-p-hydroxy benzoichydrazone (HNHBH) Spectrophotometrically, J. Der. Pharma. Chemica, 7 (2015).

DOI: https://doi.org/10.9790/4861-0804045559

[10] B. Ranganath, L.K. Ravindranath, P. Venkataramana, Direct Spectrophotometric Determination of Vanadiu (V) Using 5- methoxy-2-[(4-methoxy-3, 5-dimethyl-2-pyridinyl] methyl] sulfinyl]-1H-Benzimidazole [ESMPZL], J. Appl. Chem, 8 (2015) 60-64.

[11] K.H. Kadhim , Z.H. Hameed, Spectrophotometric Determination of Vanadium Using New Analytical Reagent 7-(6-bromo-2-benzothiazolylazo)-8‏- hydroxyquinoline, J. Iraqi. Chem, 56 (2014) 381-393.

[12] R. Gurkan, H.I. Ulusoy, A. Tamay, Speciative Determination of Total V And Dissolved Inorganic Vanadium Species in Environmental Waters by Catalytic–Kinetic Spectrophotometric Method, Arab. J. Chem, (2012)‏. In Press.

DOI: https://doi.org/10.1016/j.arabjc.2012.06.006

[13] Q.Z. Zhai, X.X. Zhang, G. Huang, Kinetic-Spectrophotometric Determination of Trace Amounts of Vanadium(V) Based on Its Catalytic Effect on The Reaction of DBM-Arsenazo and Potassium Bromate, J. Spectrochim. Acta. 69 (2008) 911–916.

DOI: https://doi.org/10.1016/j.saa.2007.05.054

[14] M. Keyvanfard, Kinetic-Spectrophotometric Determination of Trace Amounts of Vanadium (V) Based on its Catalytic Effect on the Oxidation of Victoria Blue B by Potassium Bromate in Micellar Medium, J. World. Appl. Sci. 6 (2009) 624-629‏.

[15] R. Gurkan, O. Gurkan, Catalytic-Kinetic Spectrophotometric Determination of Vanadium (V) Based on Celestine Blue-Bromate-Vanadium (V)-Citric Acid Reaction, J. Rare. Metals. 30 (2011) 348-358. ‏.

DOI: https://doi.org/10.1007/s12598-011-0396-0

[16] R.A. Hofstader, O.I. Milner, J.M. Runnels, Analysis of Petroleum for Trace Metals, Copyright, Advances in Chemistry Series, Forewor , J. Amer. Chen. Soc., Washington. D. C. USA. 156 (1976) 1-6. ‏.

DOI: https://doi.org/10.1021/ba-1976-0156

[17] Trace Metals in Petroleum Products or Organics by AAS, Universal oil products (UOP) method (1995) 391.

[18] M. Kopanica A.L. Et, Kinetic Methods in Chemical Analysis, J. Elsevier, Amsterdam, The Netherlands. (1983) 25–27. ‏.

[19] D. Pérsez-Bendito, M. Silva, Kinetic Methods in Analytical Chemistry, J. John Wiley and sons, New York (1988).

[20] Jn. ‏ Miller, Jc. Miller, Statistics and Chemometrics for Analytical Chemistry, J. Prentice Hall, England. (2005).

Show More Hide