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Dependence of Storage Material Surfaces on the Oxidative Rancidity Kinetics of Peanut Oil

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The rates of oxidative rancidity of peanut oil in contact with iron, copper, zinc, aluminum, tin, polyethylene (PE), glass and magnesium were studied. The rancidity of the oil in the surfaces made of these materials decreased in the order Mg>Fe>Cu>Sn>Glass>Zn>Al>PE. The order obtained showed that the rancidity process does not depend on the activity of these surfaces, but has a possible link with surface passivity. The values for the rate of rancidity in Mg and Fe surfaces where the process was fastest were 2.08 × 10-5 and 1.39 × 10-5 mmolkg-1hr-1 respectively, while values for the lowest rates of rancidity obtained for Al and PE surfaces were 2.78 × 10-6 and 1.07 × 10-6 mmolkg-1hr-1 respectively. The use of aluminum and PE vessels for the storage of peanut oil would increase its shelf-life by keeping the oil in its original state for a longer period of time.


International Letters of Chemistry, Physics and Astronomy (Volume 65)
C. E. Duru et al., "Dependence of Storage Material Surfaces on the Oxidative Rancidity Kinetics of Peanut Oil", International Letters of Chemistry, Physics and Astronomy, Vol. 65, pp. 27-31, 2016
Online since:
Apr 2016

[1] K. Treadwall, C. Young and J.C. Wynne, Evaluation of fatty acid components of forty peanut oil cultivars, Oleagineux 38 (1983) 381-388.

[2] M.H. Gordon, The development of oxidative rancidity, in: J. Pokorny, N. Yanishlieva, M. Gordon (Eds. ), Antioxidants in Food – Practical Applications, CRC Press, Washington, (2001) p.7–22.

DOI: 10.1201/9781439823057

[3] E.N. Frankel, Oxidation of polyunsaturated lipids and its nutritional consequences. Oils-Fats-Lipids, in: Proceedings of the 21st World Congress of the ISF, Vol. 2, PJ Barnes and Associates, Bridgwater, (1996) p.265–269.

[4] F. Doleschall, Z. Kemény, K. Recseg, K. Kõvári, Monitoring of lipid degradation products by solid-phase microextraction. J. Microcolumn Separations, 13, (2001) 215–220.

DOI: 10.1002/mcs.1045

[5] R.J. Hamilton, C. Kalu, E. Prisk, F.B. Padley, H. Pierce, Chemistry of free radicals in lipids. Food Chem., 60, (1997) 193–199.

DOI: 10.1016/s0308-8146(96)00351-2

[6] E.N. Frankel, Chemistry of autoxidation: mechanism, products and flavor significance. in: D. B, Min, T.H. Smouse (Eds. ), Flavor Chemistry of Fats and Oils, AOCS, Urbana-Champaign, (1995) p.1–38.

[7] I. Medina, M.T. Satué-Gracia, E.N. Frankel, Static headspace gas chromatographic analyses to determine oxidation of fish muscle lipids during thermal processing. J. Am. Oil Chem. Soc., 76, (1999) 231–236.

DOI: 10.1007/s11746-999-0223-z

[8] J. Pikul, Lipid oxidation and warmed-over flavour formation in heated and stored meat. Part II. Gosp. Miêsna, 8, (1992) 22–26.

[9] G. Pristouri, A. Badeka and M.G. Kontominas, Effect of packaging material headspace, oxygen and light transmission, temperature and storage time on quality characteristics of extra virgin olive oil, Food Control, 21 (2010) 412–418.

DOI: 10.1016/j.foodcont.2009.06.019

[10] A. Tsimis and N.G. Karakasides, How the choice of container affects olive oil quality- a review, Packaging Technology and Science, 15 (2002) 147-154.

DOI: 10.1002/pts.581

[11] S. Dabbou, I. Gharbi, S. Dabbou, F. Brahmi, A. Nakbi and M. Hammami, Impact of packaging material and storage time on olive oil quality, African Journal of Biotechnology, 10(74) (2011) 16937-16947.

DOI: 10.5897/ajb11.880

[12] M.A. Del Nobile, S. Bove, E. La Notte, and R. Sacchi, Influence of packaging geometry and material properties on the oxidation kinetics of bottled virgin olive oil, Journal of Food Engineering, 57 (2003) 189–197.

DOI: 10.1016/s0260-8774(02)00297-2

[13] A.K. Kiritsakis, and L.R. Dugan, Effect of selected storage conditions and packaging materials on olive oil quality, Journal of the American Oil Chemists' Society, 61 (1984) 1868-1870.

DOI: 10.1007/bf02540820

[14] M.R. Grover, Studies on shelf-life of vegetable oils packed in tin containers, Journal of Food Science and Technology, 19 (1982) 268-270.

[15] A. Mendez and E. Falque, Effect of storage time and container type on the quality of extra-virgin olive oil, Food Control, 18(5) (2007) 521-529.

DOI: 10.1016/j.foodcont.2005.12.012

[16] F.M. Farhan and H. Pazandeh, Determination of traces of heavy metals in oils and fats by arc spectrography. J. American Oil Chemists Society, 53(5) (1976) 211-213.

DOI: 10.1007/bf02633307

[17] AOAC, Official Methods of Analysis of the Association of Official Analytical Chemist. Method Number 965. 33b. AOAC Inc., Washington, US (1995).

[18] B. Halliwell and J.M.C. Gutteridge, Oxygen toxicity, oxygen radicals, transition metals and diseases, Biochemical Journal, 218, (1984) 1-14.

[19] D.A. Tsimis and N.G. Karakasides, How the choice of container affects olive oil quality, Packaging Technology and Science, 15 (2002) 147-154.

DOI: 10.1002/pts.581
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