Subscribe

Subscribe to our Newsletter and get informed about new publication regulary and special discounts for subscribers!

ILCPA > Volume 62 > Electron Accepting...
Electron Accepting Benzodithiophene-4,8-Dicarboxylate Designed for New Type D-A Narrow Bandgap Copolymers
< Back to Volume

Electron Accepting Benzodithiophene-4,8-Dicarboxylate Designed for New Type D-A Narrow Bandgap Copolymers

Full Text PDF

Abstract:

An acceptor (A) unit of benzodithiophene-4,8-dicarboxylate (BDTC) was combined with a donor (D) unit of thieno (3,4-d) thiazole (TTz) to synthesize a D-A type conjugated polymer, PBDTC-TTz. Bandgap of PBDTC-TTz was narrow, estimated to be 1.57 eV. The π-stacking distance observed by XRD was small value to be 3.55 Å. The energy level of the highest occupied molecular orbital was estimated to be ‒5.03 eV, which was deeper than that another D-A type copolymer composed of BDTC and thieno (3,4-b) thiophene, previously synthesized.

Info:

Periodical:
International Letters of Chemistry, Physics and Astronomy (Volume 62)
Pages:
37-41
DOI:
https://doi.org/10.18052/www.scipress.com/ILCPA.62.37
Citation:
K. Shibasaki and M. Kijima, "Electron Accepting Benzodithiophene-4,8-Dicarboxylate Designed for New Type D-A Narrow Bandgap Copolymers", International Letters of Chemistry, Physics and Astronomy, Vol. 62, pp. 37-41, 2015
Online since:
November 2015
Authors:
Kosuke Shibasaki, Masashi Kijima
Keywords:
Benzodithiophene, Donor-Acceptor Conjugated Polymer, Thienothiazole
Export:
RIS, BibTeX, Text
Distribution:
Open Access

Creative Commons License
This work is licensed under a
Creative Commons Attribution 4.0 International License

References:

[1] K. Shibasaki, K. Tabata, Y. Yamamoto, Y. Yasuda, M. Kijima, Macromolecules 47 (2014) 4987-4993.

[2] A. K. Agrawal, S. A. Jenekhe, Chem. Mater. 8 (1996) 579-589.

[3] J. W. Jo, S. S. Kim, W. H. Jo, Org. Electron. 13 (2012) 1322-1328.

[4] P. D. Homyak, J. Tinkham, P. M. Lahti, E. B. Coughlin, Macromolecules 46 (2013) 8873-8881.

[5] N. Allard, S. Beaupré, B. R. Aïch, A. Najari, Y. Tao, M. Leclerc, Macromolecules 44 (2011) 7184-7187.

Show More Hide
Cited By:
This article has no citations.