Synthesis, Spectral and Computational Studies of some 2-(2-(3-Methyl-2,4-Diphenyl-3-Azabicyclo[3.3.1]Nonan-9-Ylidene)Hydrazinyl)Benzo[d]Thiazole Derivatives

Sundararajan, G.; Rajaraman, D.; Bharanidharan, S.; Krishnasamy, K.

doi:10.18052/www.scipress.com/ILCPA.61.28

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Synthesis, Spectral and Computational Studies of some 2-(2-(3-Methyl-2,4-Diphenyl-3-Azabicyclo[3.3.1]Nonan-9-Ylidene)Hydrazinyl)Benzo[d]Thiazole Derivatives

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Abstract:

A series of some 2-(2-(3-methyl-2,4-diphenyl-3-azabicyclo [3.3.1] nonan-9-ylidene) hydrazinyl) benzo [d] thiazole derivatives 11-14 have been synthesized using acetic acid as the catalyst. All the synthesized compounds were characterized by FT-IR, ¹H ¹³C NMR and HSQC spectral analysis. The molecular modelling was carried out for compound 11 by Gaussian 03W package and its HOMO–LUMO, Mulliken atomic charges, Molecular electrostatic potential (MEP), Hyperpolarizability, Thermodynamic propeties and Natural bond orbital (NBO) analysis were discussed

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Periodical:

International Letters of Chemistry, Physics and Astronomy (Volume 61)

Pages:

28-37

DOI:

https://doi.org/10.18052/www.scipress.com/ILCPA.61.28

Citation:

G. Sundararajan et al., "Synthesis, Spectral and Computational Studies of some 2-(2-(3-Methyl-2,4-Diphenyl-3-Azabicyclo[3.3.1]Nonan-9-Ylidene)Hydrazinyl)Benzo[d]Thiazole Derivatives", International Letters of Chemistry, Physics and Astronomy, Vol. 61, pp. 28-37, 2015

Online since:

November 2015

Authors:

G. Sundararajan, D. Rajaraman, S. Bharanidharan, K. Krishnasamy

Keywords:

2-Hydrazinobenzothiazole, Bicyclic Piperidones, HOMO-LUMO, NLO

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Creative Commons Attribution 4.0 International License

References:

[1] F. Shabani, S. Ghammamy, J. Chem. Pharm. Res. 2 (2010) 1–6.

[2] Z.H. Chohan, M. Arif, Z. Shafiq, M. Yaqub, C.T. Supuran, J. Enzym. Inhib. Med. Chem. 21 (2006) 95–103.

[3] M. Bakir, I. Hassan, T. Johnson, O. Brown, O. Green, C. Gyles, M.D. Coley, J. Mol. Struct. 688 (2004) 213–222.

[4] J. Badan, R. Hierle, A. Perigaud, J. Zyss, in: D.J. Williams (Ed. ), Nonlinear Optical Properties of Organic Molecules and Polymeric Materials, American Chemical Symposium Series 233, American Chemical Society, Washington, DC, (1993).

[5] C.W. Dirk, H.E. Katz, M.L. Schilling, L.A. King, Chem. Mater. 2 (1990) 700–705.

[6] K. Mahanalingam, M. Nethaji, P.K. Das, J. Mol. Struct. 378 (1996) 177–188.

[7] M. Rubiralta, E. Giralt, A. Diel, Piperidine Structure, Preparation and Synthetic Applications of Piperidine and its Derivatives, Elsevier, Amsterdam, (1991).

[8] R. Venkatasa Perumal, M. Adiraj, P. Shanmuga Pandian, Indian Drugs 38 (2001) 156.

[9] V.N. Nesterov, T.V. Timofeeva, S.S. Sarkisov, A. Leyderman, C.Y. Lee, M.Y. Antipin, Acta Crystallogr. 59 (2003) 605.

[10] R. Sampathkumar, R. Sabesan, S. Krishnan, J. Mol. Liq. 116 (2005) 1.

[11] A.B. Garcia, C. Valdes, M. Paz Cabal, Tetrahedron Lett. 45 (2004) 4357.

[12] F. Diwischek, M. Arnone, B. Engels, U. Holzgrabe, Tetrahedron 61 (2005) 6993.

DOI: https://doi.org/10.1016/j.tet.2005.05.030

[13] Valverde MG, Torroba T (2005) Synthesis of new multidentate sulphur heterocycles and metal, complexes structural studies. Molecules 10: 318–320.

[14] V. Baliah, R. Jeyaraman, Synthesis of some 3-azabicyclo[3. 3. 1]nonan-9-one, Indian. J. Chem. 9 (1971) 1020-1022.

[15] Balasubramanian M.; Padma N. Tetrahedron 19(1963) 2135.

[16] Dua R, Sonwane SK, Srivastava SK, Srivastava SD (2010).

[17] R.M. Silverstein, F.X. Webster, Spectrometric Identification of Organic Compounds, sixth ed. Wiley, New York, 1998, 209.

[18] R.M. Silverstein, F.X. Webster, Spectrometric Identification of Organic Compounds, sixth ed. Wiley, New York, 1998, 229.

[19] M.J. Frisch, G.W. Trucks, H.B. Schlegel, G.E. Scuseria, M.A. Robb, J.R. Cheeseman, J.A. Montgomery, Jr., T. Vreven, K.N. Kudin, J.C. Burant, J.M. Millam, S.S. Iyengar, J. Tomasi, V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, G.A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, M. Klene, X. Li, J. E. Knox, H.P. Hratchian, J.B. Cross, C. Adamo, J. Jaramillo, R. Gomperts, R.E. Stratmann, O. Yazyev, A.J. Austin, R. Cammi, C. Pomelli, J.W. Ochterski, P.Y. Ayala, K. Morokuma, G.A. Voth, P. Salvador, J.J. Dannenberg, V.G. Zakrzewski, S. Dapprich, A.D. Daniels, M.C. Strain, O. Farkas, D.K. Malick, A.D. Rabuck, K. Raghavachari, J.B. Foresman, J.V. Ortiz, Q. Cui, A.G. Baboul, S. Clifford, J. Cioslowski, B.B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R.L. Martin, D.J. Fox, T. Keith, M.A. Al-Laham, C.Y. Peng, A. Nanayakkara, M. Challacombe, P.M.W. Gill, B. Johnson, W. Chen, M.W. Wong, C. Gonzalez, J.A. Pople, Gaussian-03(program), Inc., Pittsburgh PA, (2003).

[20] H.B. Schlegel, J. Comput. Chem. 3 (1982) 214–218.

[21] I. Sidir, Y.G. Sidir, M. Kumalar, E. Tasal, J. Mol. Struct. 964 (2010) 134-151.

[22] P. Politzer, P.R. Laurence, K. Jayasuriya, Environ. Health Perspect. 61 (1985) 191–202.

[23] M.A. Palafox, Int. Quant. J. Chem. 77 (2000) 661.

[24] C. Castiglioni, M. Del zoppo, P. Zuliani, G. Zerbi, Synth. Met. 74 (1995) 171–177.

[25] P. Zuliani, M. Del zoppo, C. Castiglioni, G. Zerbi, S.R. Marder, J.W. Perry, Chem. Phys. 103 (1995) 9935.

[26] M. Del zoppo, C. Castiglioni, G. Zerbi, Non-Linear Opt. 9 (1995) 73.

[27] M. Del zoppo, C. Castiglioni, P. Zuliani, A. Razelli, G. Zerbi, M. Blanchard-Desce, J. Appl. Polym. Sci. 70 (1998) 73.

DOI: https://doi.org/10.1002/(sici)1097-4628(19981114)70:7<1311::aid-app8>3.3.co;2-y

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