Acoustical Studies of Ternary Liquid Mixtures of 2-Aminothiazole in DMF-Water at Different Temperatures

Morey, P.B.; Naik, A.B.

doi:10.18052/www.scipress.com/ILCPA.59.188

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Acoustical Studies of Ternary Liquid Mixtures of 2-Aminothiazole in DMF-Water at Different Temperatures

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Abstract:

The nature and the relative strength of the intermolecular interaction between the components of the liquid mixtures have been successfully investigated by ultrasonic method. In present study, the densities (ρ), ultrasonic velocities (u), viscosity (ɳ) and refractive index (n_D) in a ternary liquid mixture of 2-aminothiazole with N,N-dimethylformamide (DMF) in water have been measured at 303.15, 308.15, 313.15,318.15 and 323.15 K respectively, over the entire composition range by using densitometer, ultrasonic interferometer, viscometer and refractmeter respectively. The measured data have been used to compute the various thermo-acoustic parameters using the standard relations namely, adiabatic compressibility (β_s), intermolecular free length (L_f), specific acoustic Impedance (Z),Wada constant (W), molar sound velocity (R), relative association (R_A), apparent molar compressibility (),apparent molar volume () viscosity relaxation time (Г),absorption coefficient, internal pressure (ᴨ),free volume (V_f),Gibb҆ s free energy (∆G) and specific refraction (r), etc. The results have been analyzed on the basis of variation in thermodynamic parameters. These parameters are useful for explaining the molecular association and interaction between the components of ternary liquid mixtures. The variation in densities and ultrasonic velocities with concentrations in the system show similar trends for evaluated parameters of the constituents in ternary mixture at different temperatures. The results have been interpreted in terms of solute-solvent and solvent-solvent interaction.

Info:

Periodical:

International Letters of Chemistry, Physics and Astronomy (Volume 59)

Pages:

188-198

DOI:

https://doi.org/10.18052/www.scipress.com/ILCPA.59.188

Citation:

P.B. Morey and A.B. Naik, "Acoustical Studies of Ternary Liquid Mixtures of 2-Aminothiazole in DMF-Water at Different Temperatures", International Letters of Chemistry, Physics and Astronomy, Vol. 59, pp. 188-198, 2015

Online since:

September 2015

Authors:

P.B. Morey, A.B. Naik

Keywords:

2-Aminothiazole, Adiabatic Compressibility, Density, DMF, Molecular Interaction, Ternary Mixture, Thermo-Acoustic, Ultrasonic Velocity

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Creative Commons Attribution 4.0 International License

References:

[1] S. Baluja, R. Talaviya, K. Bhesaniya, J. Chem. Bio. Phy. Sci. Sec . A 3(4) (2013) 2438-2445.

[2] V. Kannappan , S. Xavier, Jaya Santi, Indian J. pure Appl. Phys. 41(2003) 690.

[3] A.B. Naik, M.L. Narwade, P. S. Bodakhe, G.G. Muley, Russ.J. Physical Chem. 88 (1) (2014) 37-41.

[4] Attri Pankaj, P. Reddy, Madhusudhanand Venkatesu, Ind. J. chem. 49A (2010)736-742.

[5] T.F. Cruz, A. Mogon, W. Min, Mol. Bio-chem. 153(1995)161.

[6] S.S.J. Srinivas, B. Tulsi Koteswari Bai, K. Babu Rao, K. Narendra, M. Sarath Babu, International Letters of Chemistry, Physics and Astronomy 10(2)(2013) 33-40.

[7] E. Zagar and M. Zigon, Polymer, 41(2000) 3513.

[8] Y.K. Kang and H.S. Park, J. Mol Struct(Theochem) 676 (2004)171.

[9] J. Dean, A. Lange's, Hand Book of Chemistry, McGraw-Hill, NewYork (1956).

[10] Y. Umebayashi, K. Matsumoto, M. Watanabe, S. Ishiguro, J. Chem. Phys, 3(2001)5475.

[11] P. Venkesu, M.J. Lee ,H.M. Lin, J. chem. Thermo, 53 (2005) 996).

[12] C.H. Srinivasu , K. Anil Kumar, S. K. Fakruddin, K. Narendra, T. Anjaneyul, International Letters of Chemistry, Physics and Astronomy 13 (2013) 1-7.

[13] A.N. Kannapan, Thirumaran., Palanichammy, J. of Physical sci, vol. 20(2), (2009) 97-108.

[14] C. Gopi and N. Santhi, International Letters of Chemistry, Physics and Astronomy 17(1) (2014) 50-66.

[15] H. Eyrin, J.F. Kincad, J. Chem. Phys, 6(1938) 620-629.

[16] K.C. Patil and V.D. Umare, Int.J. Resh. in Pure app. Phys, 2(4); (2012) 25-27.

[17] A. Pal, H. Kumar, R. Mann, H. K. Sharma, J. Chem. Eng. Data 58 (2013) 3190-200.

[18] R. K. Bachu, M. K. Patwari, S. Boodida, S. J. Tangeda, S. Nallani, Ind. J. Chem. 47A (2008) 1026.

[19] S. J. Kharat, Physics Chemistry liqs. 51 (2013) 1-10.

[20] S. Padma, There., Rasayan J. Chem 6(2)(2013) 111.

[21] G.R. Bedare, V.D. Bhandakkar and B. M. Suryvanshi, Ind. J. Res. Pure & Appl. Phys. 3(3) (2013) 20-25.

[22] R. Mohanty and R. Paikaray, Res. J. of Chem. Sci. 3(5) (2013) 71-73.

[23] S. Nithiyanantham and Palaniappan chem. sci. Trans., 2(1) (2013) 35-40.

[24] Zareena Begaum, et. al., J. Mol. Liqs, 178 (2013) 99-112.

[25] G. Pavan Kumar, Ch. Pravin Babu,K. Samatha, N. Jyosthna,K. Showrilu, International Letters of Chemistry, Physics and Astronomy 10 (2014) 25-37.

DOI: https://doi.org/10.18052/www.scipress.com/ilcpa.29.25

[26] N. Santhi, P.L. Sabarathinam, J. Madhumita, G. Alanelumangai,M. Emayavaramban, International Letters of Chemistry, Physics and Astronomy 2 (2013) 18-35.

[27] N. Santi, J. Madhumita. Int. J. Adv. Chem. 2(1), (2014) 12-16.

[28] S. Baluja and A. Shah, Russ.J. Phys. Chem. 80 (7) (2006) 1-5.

[29] S. Pal and S. Kumar, J. Mol. Lids., 109 (2004) 23-31.

[30] K. Narendra, P. Narayanamurthy and Ch. Srinivasu. Asian J. of Appl. Sci., 10 (2011)1-7.

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DOI: https://doi.org/10.1016/j.protcy.2016.05.186

[2] A. Naik, M. Poharkar, "Stability Constant of Rare Earth Metals with Substituted Thiazoles at 298.15K", International Letters of Chemistry, Physics and Astronomy, Vol. 64, p. 106, 2016

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