XPS Study of Sol-Gel Synthesized Vanadium-Titanium-Hydroquinone Oxide Bronze Films

Bondarenka, Vladimiras; Sereika, R.

doi:10.18052/www.scipress.com/ILCPA.54.201

ILCPA > ILCPA Volume 54 > XPS Study of Sol-Gel Synthesized...

< Back to Volume

XPS Study of Sol-Gel Synthesized Vanadium-Titanium-Hydroquinone Oxide Bronze Films

Full Text PDF

Abstract:

Vanadium-titanium-hydroquinone oxide bronze, V_1.67Ti_0.33O_5±δ /HQ (HQ-hydroquinone), was synthesized by using the sol–gel method. Vanadium pentoxide powder, titanium dihydride, hydrogen peroxide and hydroquinone were used as the starting materials to produce bronze. The composition of the synthesized compound was compared with V_1.67Ti_0.33O_5±δ∙nH₂O/HQ xerogel data. The xerogel and bronze were investigated by means of the XPS method. Analysis of the V–O region of XPS spectra showed that vanadium ions in xerogel ocurr in V⁵⁺ and V⁴⁺ states. In bronze, these ions are in a stable V⁵⁺state. The oxygen in xerogel can be associated with O^2- ions, hydroxide grouping and water. Oxygen only exists in bronze in the form of O^2- ions and hydroxyl groups. Titanium ions in both cases are in a stable Ti⁴⁺ state.

Info:

Periodical:

International Letters of Chemistry, Physics and Astronomy (Volume 54)

Pages:

201-207

DOI:

https://doi.org/10.18052/www.scipress.com/ILCPA.54.201

Citation:

V. Bondarenka and R. Sereika, "XPS Study of Sol-Gel Synthesized Vanadium-Titanium-Hydroquinone Oxide Bronze Films", International Letters of Chemistry, Physics and Astronomy, Vol. 54, pp. 201-207, 2015

Online since:

July 2015

Authors:

Vladimiras Bondarenka, R. Sereika

Keywords:

Hydroquinone, Sol-Gel Technology, Valence States of Ions, Vanadium Oxides, X-Ray Photoelectron Spectroscopy

Export:

RIS, BibTeX, Text

Distribution:

Open Access

This work is licensed under a
Creative Commons Attribution 4.0 International License

References:

[1] Legendre, J. -J., Livage, J. J. Colloid. Interf. Sci. 94 (1983): 75-83.

[2] Legendre, J. -J., Aldebert, P., Baffer, N., Livage, J. J. Colloid Interf. Sci. 94 (1983): 84-89.

[3] Volkov, V. L., Zakharova, G. S., Bondarenka, V. Xerogels of Simple and Complex Polyvanadates,. Ural Branch of Russian Academy of Sciences, Yekaterinburg, (2001).

[4] Bondarenka, V. , Pašiškevicius, A., Volkov, V. L., Zakharova, G. S. Lith. J. Phys. 47 (2007): 59-62.

[5] Huguenin, F., Girotto, E. M., Torresi, R. M, Buttry, D. A. J. Electroanal. Chem. 536 (2002): 37-45.

[6] Nakato, T., Ise, T., Sugahara, Y., Kuroda, K., Kato, Ch. Mater. Res. Bull. 26 (1991): 309-315.

[7] Aldebert, P., Baffer, N., Gharbi, N., Livage, J. Mater. Res. Bull. 16 (1981): 949-955.

[8] Volkov, V. L., Zakharova, G. S., Kuznetsov, M. V., Jin, A., Zhu, Q., Chen, W. Russian J. Inorg. Chem. 51 (2006): 1339-1344.

[9] Hagenmuller, P., Galy, J., Pouchard, M., Casalot, A. Mater. Res. Bull. 1 (1966): 95-107.

[10] Evans, H. T., Hughes, J. M., Am. Mineralogist 75 (1990): 508-521.

[11] Chirayil, T. A., Zavalij, P. Y., Whittingham, M. C. Chem. Mater. 10 (1998): 2629-2640.

[12] Zhang, F., Zavalij, P. Y., Whittingham, M. C., Electrochem. Commun. 1 (1999): 564-567.

[13] Česnys, A., Tvardauskas, H., Martūnas, Z., Oginskis, A. K., Lith. J. Phys. 41 (2001): 119-123.

[14] Česnys, A., Bondarenka, V. , Oginskis, A., Latyshenka, A. Lisauskas, V. J. Solid State Chem. 113 (1994): 438-440.

[15] Livage, J. Coord. Chem. Rev. 178-180 (1998): 999-1018.

[16] Livage, J., Chem. Mater. 3 (1991): 578-593.

[17] Kweon, H., Lee, K. W., Lee, E. M., Park, J., Kim, I. M., Lee, C. E., Jung, G., Gedanken, A., Koltypin, Y. Phys. Rev. B 76 (2007): 045434.

[18] Wang, X., Liu, L., Jacobson, A. J., Agew. Chem. Intern. Ed. 45 (2006): 1-5.

[19] Bonadarenka, V., Jasulaitienė, V., Sereika, R., Stirkė, A. J. Sol-Gel Sci. Technol. 71 (2014): 385-390.

[20] Bondarenka, V., Tvardauskas, H., Grebinskij, S., Senulis. M., Pašiškevičius, A., Volkov, V. Zakharova, G., Phys. Stat. Sol. C. 6 (2009): 2807-2809.

DOI: https://doi.org/10.3952/lithjphys.49207

[21] Nefedov, V. I., Gati, D., Dzhurinskii, B. F., Segushin, N. P., Salyn, Y. A. Russian J. Inorg. Chem. 20 (1975): 2307-2314.

[22] Moulder, J. F., Stickle, W. F., Sobol, P. E., Bomben, K. D. Handbook of X-ray Photoelectron Spectroscopy Physical Electronics. Minnesota: Eden Praire, (1995).

[23] Bondarenka, V. Tvardauskas, H. Grebinskij, S. Mickevičius, S., Martūnas, Z., Volkov, V. Zakharova, G. Nucl. Instrum. Methods B. 178 (2001): 323-326.

[24] Bondarenka, V., Grebinskij, S., Mickevičius, S., Kačiulis, S., Pandolfi, L., Volkov, V., Zakharova, G. Lith. J. Phys. 43 (2003): 309-313.

[25] Borgmann, D., Hums, E., Hopfengärtner, G., Wedler, G., Spitznagel, G. W., Rademacher, I. J. Electron. Spectrosc. Relat. Phenom. 63 (1993): 91-116.

[26] Bondarenka, V., Grebinskij, S., Mickevičius, S., Tvardauskas, H., Kačiulis, S., J. Alloys Compd. 382 (2004): 239-243.

DOI: https://doi.org/10.1016/j.jallcom.2004.06.005

[27] Bondarenka, V., Grebinskij, S., Mickevičius, S., Tvardauskas, H., Kačiulis, S., Volkov, V., Zakharova, G., Pašiškevičius, A. Lith. J. Phys. 47 (2007): 333-342.

[28] Mancia, F., Fierro, G., Ingo, M. Corrosion 45 (1989): 814-823.

[29] Yang, W. P., Costa, D., Marcus, P., J. Electrochem. Soc. 141 (1994): 2669-2676.

[30] Brox, B., Olefjord, I., Jelvestam, U., J. Electrochem. Soc. 132 (1985): 2854-2864.

[31] Bondarenka, V., Martūnas, Z., Kačiulis, S., Pandolfi, L. J. Electron. Spectrosc. Relat. Phenom. 131-132 (2003): 99-103.

[32] Bondarenka, V., Grebinskij, S., Martūnas, Z., Mickevičius, S., Tvardauskas, H. Kačiulis, S., Pandolfi, L., Volkov, V., Podvalnaia, N. Lith. J. Phys. 46 (2006): 185-190.

[33] Bondarenka, V., Kačiulis, S., Martūnas, Z., Rėza, A., Babonas, G. J., Pašiškevičius, A. Lith. J. Phys. 48 (2008): 341-348.

[34] Freyer, N., Pirug, G., Bonzel, H. P., Freyer, N., Surf. Sci. 126 (1983): 487-494.

[35] Meenan, B. J., Hewitt, J. A., Brown, N. M. D., Surf. Interface Anal. 18 (1992): 187-198.

Show More Hide

Cited By:

This article has no citations.