Subscribe

Subscribe to our Newsletter and get informed about new publication regulary and special discounts for subscribers!

ILCPA > Volume 5 > Ultrasonic Study of Molecular Interaction in...
Ultrasonic Study of Molecular Interaction in Binary Liquid Mixtures of n-Hexane with Alcohols
< Back to Volume

Ultrasonic Study of Molecular Interaction in Binary Liquid Mixtures of n-Hexane with Alcohols

Full Text PDF

Abstract:

Ultrasonic velocity, viscosity and density of alcohol[s] in n-hexane have been measured at various temperatures in the range of 303.15 - 318.15K. From the experimental data, the acoustical parameters such as molar volume, adiabatic compressibility, intermolecular free length and their excess values have been computed and presented as functions of compositions. The deviations from ideality of the acoustical parameters are explained on the basis of molecular interactions between the components of the mixtures. The variations of these parameters with composition of the mixture suggest the strength of interactions in these mixtures.

Info:

Periodical:
International Letters of Chemistry, Physics and Astronomy (Volume 5)
Pages:
59-71
DOI:
https://doi.org/10.18052/www.scipress.com/ILCPA.5.59
Citation:
N. Santhi et al., "Ultrasonic Study of Molecular Interaction in Binary Liquid Mixtures of n-Hexane with Alcohols", International Letters of Chemistry, Physics and Astronomy, Vol. 5, pp. 59-71, 2012
Online since:
September 2013
Authors:
N. Santhi, P.L. Sabarathinam, G. Alamelumangai, J. Madhumitha, M. Emayavaramban
Keywords:
Acoustical Parameters, Alcohol, Mixtures, n-Hexane
Export:
RIS, BibTeX, Text
Distribution:
Open Access

Creative Commons License
This work is licensed under a
Creative Commons Attribution 4.0 International License

References:

[1] Richardson E. G., Brown A. E., Phil Mag 4 (1959) 705.

[2] Seshagiri Rao M. G., Rao B. R., J. Sci, Industr. Res. 21B (1961) 331.

[3] Reddy K. C., Subrahmanyam S. V., Bhimasenachar J., J. Physic. Soc. Japan 19 (1964) 559.

[4] Prakash S., Srivastav S. B., Prakash D., Indian J. Pure and Appl. Phys. 13 (1975) 191.

[5] Prasad N., Prakash S., Acustica. 36 (1976) 313.

[6] Fort R. J., Moore W. R., Trans, Faraday So. 61 (1965) 2102.

[7] Desh Pande D. D., Bhatgadde L. G., J. Phys. Chem. 72 (1968) 261.

[8] Snyder W. J., Snyder J. R., J. Chem. Engg. Data 19 (1974) 270.

[9] Seshadri K., Rao N. P., Reddy K. C., Z. Physik, Chem (N. F) 89 (1974) 109.

[10] Kaulgud M. V., Patil K. J., Indian Pure and Appl. Phys. 13 (1975) 322.

[11] Ali A., Nain A. K., J. Pure Appl. Ultrason. 24 (2002) 97.

[12] Sudhanshu S. N., Napal S., Bhattrai G. P., Adhikari M. P., J. Pure Appl. Ultrason. 24 (2002) 78.

[13] Baluja S., Oza S., J. Pure Appl. Ultrason., 22, (2000) 10.

[14] Raut B. K., Chakaravortty V., J. Chem. 33A (1994).

[15] Moelwyn Hughes E. A., Thorpe P. L., Proc. Roy. Soc. London 268 (1964) 574.

[16] Prakash S., Srivastava S. B., Chem, Thermodynamics 7 (1975) 997.

[17] Vileu R., Simion A., Rev. Roum, Chim 21 (1976) 117.

[18] Tumikoski F., Nurmi V., Comments Phys. Math Helsingf 10 (1940) 11.

[19] Fort R. J., Moore W. R., Trans Faraday Soc. 62 (1966) 1112.

[20] Flory P. J. J., Amer . Chem. Soc. 87 (1965) 1833.

[21] Abe A., Flory P. J. J., Amer. Chem. Soc. 87 (1965) 1838.

[22] Prakash S., Prasad N., Singh R., Prakash O., Acustica 34 (1975) 121.

[23] Kumar A., Prakash O., Prakash S., J. Chem. Eng. Data 26 (1981) 64.

[24] Raman G. K., Naidu P. R., Proc . Inidan Acad. Sc. 77 (1973) 263.

[25] Lagemann R. T., Dunbar W. S., N. J . Phys, Chem. 49 (1945) 428.

[26] Weissler A. J., Amer. Chem. Soc. 71 (1949) 1272.

[27] Rao M. R., J. Chem. Phys. 9 (1941) 682.

[28] Bahl and Arun Bahl, Text book of organic chemistry 17 (2005) 292.

[29] Weissberger A., Technique of organic chemistry, Interscience Newyork, 2(7) (1955).

[30] Jacobson B., Acta Chem Scand 6 (1952) 1485.

[31] Prakash Om, Et Al., Indian J. Pure & Appl. Phys. 24 (1986) 306. Ali and A. K. Nain, Pramana. J. Physc 58(4) (2002).

[32] Aminabhavi T. M., Gopalakrishnan B., J. Chem., Eng. Data 40 (1995) 632.

[33] Venkatesulu D., Venkatesu, P., M. V. Prabhakara Rao., J. Chem. Eng. Data 42 (1997) 1145-1146.

[34] Prakash S., Sivanarayana K., Prakash Om, Can. J. Chem. 58 (1980) 942.

[35] Gour S. N., Tomar J. S., Varma R. P., Indian J. Pure & Appl. Phys. 24 (1986) 602.

[36] Gopal K., Reddy B. A., Prabhakara Rao, N., Acoustics Lett. 7(12) (1984) 197.

[37] Qrzechowki K., Ernst S., Acustica (1988) 66.

[38] Prabakar S., Rajagopal K., J. Pure Appl. Ultrason. 27 (2005) (2, 3).

[39] Bahadur Alisha S., Subha M. C. S., Rao K. C., J. Pure Appl. Ultrason. 23 (2001) 26.

[40] Guggenheim E. A., Mixtures (Oxford University Press, Oxford) (1952).

[42] Bhatti S. S., Singh, D. P., Indian J. Pure & Appl. Phys. 21 (1983) 506.

[41] Pandey P., Prakash O., Prakash S., J. Pure Appl. Ultrason. A (1982) 12.

[42] Agnihotri S. C., Prakash Om., Acustica 63 (1987) 290.

[43] Bhatti S. S., Singh, D. P., Indian J. Pure & Appl. Phys. 21 (1983) 506.

[44] Agnihotri P. K., Adgaonkar C. S., Ultrasonics 27 (1989) 248.

[45] S. Subba Rao, R. Gopalakrishna., J A S I 7(1) (1979) 5-8.

Show More Hide