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Ultrasonic Study of Molecular Interaction in Binary Liquid Mixtures of n-Hexane with Alcohols
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Ultrasonic Study of Molecular Interaction in Binary Liquid Mixtures of n-Hexane with Alcohols

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Abstract:

Ultrasonic velocity, viscosity and density of alcohol[s] in n-hexane have been measured at various temperatures in the range of 303.15 - 318.15K. From the experimental data, the acoustical parameters such as molar volume, adiabatic compressibility, intermolecular free length and their excess values have been computed and presented as functions of compositions. The deviations from ideality of the acoustical parameters are explained on the basis of molecular interactions between the components of the mixtures. The variations of these parameters with composition of the mixture suggest the strength of interactions in these mixtures.

Info:

Periodical:
International Letters of Chemistry, Physics and Astronomy (Volume 5)
Pages:
59-71
DOI:
https://doi.org/10.18052/www.scipress.com/ILCPA.5.59
Citation:
N. Santhi et al., "Ultrasonic Study of Molecular Interaction in Binary Liquid Mixtures of n-Hexane with Alcohols", International Letters of Chemistry, Physics and Astronomy, Vol. 5, pp. 59-71, 2012
Online since:
December 2012
Authors:
N. Santhi, P.L. Sabarathinam, G. Alamelumangai, J. Madhumitha, M. Emayavaramban
Keywords:
Acoustical Parameters, Alcohol, Mixtures, n-Hexane
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Distribution:
Open Access

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This work is licensed under a
Creative Commons Attribution 4.0 International License

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Cited By:

[1] S. Mohammed Hussain, R. Kumar, M. Mohamed Naseer Ali, B. Shanmugapriyan, V. Kannappan, "Unravelling various types of non-covalent interactions of benzyl amine with ethers in n – hexane at 303.15K by ultrasonic and DFT methods", Fluid Phase Equilibria, 2018

DOI: https://doi.org/10.1016/j.fluid.2018.08.001