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International Letters of Chemistry, Physics and Astronomy
Volume 49
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Study of Coordination Characteristics of some Metal Complexes of 2-Thiouracil by Infrared Spectroscopy

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Abstract:

The infrared spectra of 2-Thiouracil (Thu) have been recorded in the region 4000-400 cm-1. The assignments of fundamental frequencies have been proposed on the basis of assignments in related molecules. Correlation of vibrational assignments with those of related molecules have been pointed out. The metal ion interactions of Thu with Cd (II), Hg (II), Cu (II), and Zn (II) bromides have been investigated by infrared spectroscopy. The results are consistent with the bonding of ligands through sulphur in all the complexes. The vibrational frequencies of metal complexes of 2-Thiouracil are correlated with the spectral data of other structurally related pyrimidine thione complexes.

Info:

Periodical:
International Letters of Chemistry, Physics and Astronomy (Volume 49)
Pages:
74-80
DOI:
10.18052/www.scipress.com/ILCPA.49.74
Citation:
P. J. Rosy et al., "Study of Coordination Characteristics of some Metal Complexes of 2-Thiouracil by Infrared Spectroscopy", International Letters of Chemistry, Physics and Astronomy, Vol. 49, pp. 74-80, 2015
Online since:
Apr 2015
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