Structural Elucidation of Transition Metal Complexes of the Schiff Base of 5-Nitro Salicylaldehyde and Anthranalic Acid Using 1H NMR, Thermal Analysis, Diffused Reflectance and ESR Data

More, Paresh S.; Mehta, Bipin H.

doi:10.18052/www.scipress.com/ILCPA.48.1

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Structural Elucidation of Transition Metal Complexes of the Schiff Base of 5-Nitro Salicylaldehyde and Anthranalic Acid Using ¹H NMR, Thermal Analysis, Diffused Reflectance and ESR Data

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Abstract:

Transition metal complexes of the type ML.nH₂O [Where M= Co(II),Ni(II),Cu(II) and Zn(II), L= Schiff base of 5 nitro salicylaldehyde and anthranalic acid, n= 0,1 …..] were characterized by using ¹H NMR,TGA, Diffused refluctance and ESR spectroscopy. On the basis of above studies Co(II), Ni(II) shows tetrahedral structure, Cu(II) shows binuclear structure and Zn(II) shows square planar structure.

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Periodical:

International Letters of Chemistry, Physics and Astronomy (Volume 48)

Pages:

1-13

DOI:

https://doi.org/10.18052/www.scipress.com/ILCPA.48.1

Citation:

P. S. More and B. H. Mehta, "Structural Elucidation of Transition Metal Complexes of the Schiff Base of 5-Nitro Salicylaldehyde and Anthranalic Acid Using ¹H NMR, Thermal Analysis, Diffused Reflectance and ESR Data", International Letters of Chemistry, Physics and Astronomy, Vol. 48, pp. 1-13, 2015

Online since:

March 2015

Authors:

Paresh S. More, Bipin H. Mehta

Keywords:

5-Nitrosalicylaldehyde, ^IH NMR, Square Planar Complex, TGA

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DOI: https://doi.org/10.1016/j.molstruc.2017.05.009