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International Letters of Chemistry, Physics and Astronomy
ILCPA Volume 47

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Activated Carbon Loaded N, S Co-Doped TiO2 Nanomaterial and its Dye Wastewater Treatment

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Activated carbon (AC) loaded nitrogen and sulfur (N, S) co-doped TiO2 nanomaterial (AC-N-S-TiO2) was prepared by precipitation method. AC-N-S-TiO2 material was characterized by Scanning Electron Microscopy (SEM) with Energy Dispersive X-ray analysis (EDX), X-ray diffraction (XRD), Fourier Transform - Infrared (FT-IR), Photoluminescence (PL) and atomic force microscopy (AFM) analysis. Photodegradation and decolorization of Malachite green (MAG) and Methyl green (MEG) by using TiO2, N-S-TiO2 and AC-N-S-TiO2 under UV-light irradiation has been carried out. The photocatalytic activity of the AC-N-S-TiO2 was higher than that of the undoped and N, S-doped TiO2, The hydroxyl radical analysis - Fluorescence technique with coumarin has been discussed. The photodegradation of MEG was well described by analyzed to be pseudo-first order according to the Langmuir-Hinshelwood representation, the high quantum yield set up to be calculated, stability and reustability of nanomaterial. AC-N-S-TiO2 act as a promising photocatalyst for dye wastewater treatment under UV-light irradiation.


International Letters of Chemistry, Physics and Astronomy (Volume 47)
J. Kamalakkannan et al., "Activated Carbon Loaded N, S Co-Doped TiO2 Nanomaterial and its Dye Wastewater Treatment", International Letters of Chemistry, Physics and Astronomy, Vol. 47, pp. 147-164, 2015
Online since:
February 2015

Liu, R.; Wang, P.; Wang, X.; Yu, H.; Yu, J., J. Phys. Chem., C 2012, 116, 17721−17728.

Chandraboss, V.L.; Natanapatham, L.; Karthikeyan, B.; Kamalakkannan, J.; Prabha, S.; Senthilvelan, S., Res. Bull. 2013, 48, 3707-3712.

Chandraboss, V.L.; Senthilvelan, S.; Natanapatham, N.; Murugavelu, M.; Loganathan, B.; Karthikeyan, B. J. Non-Cryst. Solids., 2013, 368, 23-28.

Shon, H.K.; Phuntsho, S.; Vigneswaran, S, Desalin. Water Treat., 2008, 225, 235-248.

Rauf, M.A.; Meetani, M.A.; Hisaindee, S, Desalin. Water Treat., 2011, 276, 13-27.

Zhao, B.; G. Mele, G.; Pio, I.L.I.; L. Palmisano, L.; Vasapollo, G, J. Hazard. Mater., 2010, 176, 569-574.

Rengifo-Herrera, J.A. Pulgarin, C, Sol. Energy., 2010, 84, 37-43.

Dvoranova, D.; Brezova, V.; M. Mazur, M.; Malati, M. A, Appl. Catal. B: Environ., 2002, 37, 91-105.

Li, X.Y.; Yue, P.L.; Kutal, C, New J. Chem., 2003, 27, 1264-1269.

Khan, S.U.M.; Al-Shahry, M.; Ingler, W. B., 2002, 297, 2243-2245.

Yu, J.C.; Yu, J,; Ho, J.; Jiang, Z.; Zhang, L. Effects of F− doping on the photocatalytic activity and microstructures of nanocrystalline TiO2 powders. Chem. Mater. 2002, 14, 3808-3816.

Asahi, R.; Morikawa, T.; Ohwaki, T.; Aoki, K.; Taga, Y. Visible-light photocatalysis in nitrogen-doped titanium oxides. Science. 2001, 293, 269-271.

Yang, X.X.; Cao, C.D.; Erickson, L.; Hohn, K.; Maghirang, R.; Klabunde, K. Photocatalytic degradation of Rhodamine B on C-, S-, N-, and Fe-doped TiO2 under visiblelight irradiation. Appl. Catal. B: Environ. 2009, 91, 657-662.

Ma, Y.F.; Zhang, J.L.; Tian, B.Z.; Chen, F.; Wang, L.Z. Synthesis and characterization of thermally stable Sm, N co-doped TiO2 with highly visible light activity. J. Hazard. Mater. 2010, 182, 386-393.

Kuo, Y.L.; Su, T.L.; Kung, F.C.; Wu, T.J. A study of parameter setting and characterization of visible-light driven nitrogen-modified commercial TiO2 photocatalysts. J. Hazard. Mater. 2011, 190, 938-944.

Tian, H.; Ma, J.F.; Li, K.; Li, J.J. Hydrothermal synthesis of S-doped TiO2 nanoparticles and their photocatalytic ability for degradation of Methyl orange. Ceram. Int. 2009, 35, 1289-1292.

Chen, C. C; Lua, C.S.; Chung, Y.C.; Jan, J.L. UV light induced photodegradation of malachite green on TiO2 nanoparticles. J. Hazard. Mater. 2007, 141, 520-528.

Ullmann's Encyclopedia of Industrial Chemistry. Part A27. Triarylmethane and Diarylmethane Dyes; 6th ed.; Wiley-VCH; New York, (2001).

R. Bonnett, G. Martinez, Photobleaching of sensitisers used in photodynamic therapy. Tetrahedron 57 (2001) 9513-9547.

Cho, B.P.; Yang, T.; Blankenship, L.R.; Moody, J.D.; Churchwell, M.; Bebland, F.A.; Culp, S.A. Synthesis and characterization of N-demethylated metabolites of malachite green and leucomalachite green. Chem. Res. Toxicol. 2003, 16, 285-294.

Sobana, N.; Krishnakumar, B.; Swaminathan, M. Synergism and effect of operational parameters on solar photocatalytic degradation of an azo dye (Direct Yellow 4) using activated carbon-loaded zinc oxide. Mater. Sci. Semicond. Process. 2013, 16, 1046- 1051.

sun, J.H.; Wang, Y.K.; Sun, R.S.; Dong, S.V. Photodegradation of azo dye Conco Red from aqueous solution by the WO3-TiO2/ activated carbon (AC) photocatalyst under the UV irradiation. Mater. Chem. Phys. 2009, 155, 303-308.

Kumar, J.; Bansal, A. Dual effect of photocatalysis and adsorption in degradation of Azorubine dye using nanosized TiO2 and activated carbon immobilized with different techniques. Int. J. Chem. Tech. Res. 2010, 1, 1537-1543.

Chen, C.; Yu, B.; Liu, J.; Dai, Q.; Zhu, Y. Investigation of ZnO films on Si(111) substrate grown by low energy O+ assisted pulse laser deposited technology. Mater. Lett. 2007, 61, 2961-2964.

Rahmatollah Rahimi, Samaneh Safalou Moghaddam, Mahboubeh Rabbani, Comparison of photocatalysis degradation of 4-nitrophenol using N, S co-doped TiO2 nanoparticles synthesized by two different routes, J Sol-Gel Sci Technol (2012) 64: 17- 26.

Subash, B.; Krishnakumar, B.; Swaminathan, M.; Shanthi, M. Highly efficient, solar active and reusable photocatalyst: Zr-loaded Ag−ZnO for Reactive Red 120 dye degradation with synergistic effect and dye-sensitized mechanism. Langmuir. 2013, 29, 939−949.

Subramanian Balachandran, Natarajan Prakash, Kuppulingam Thirumalai, Manickavachagam Muruganandham, Mika Sillanpa and Meenakshisundaram Swaminathan, pubs. acs. dx. doi. org/10. 1021/ie404287m | Ind. Eng. Chem. Res.

K. Ameta, P. Tak, D. Soni and suresh, C. ameta. Sci. Revs. Chem. Commun., 2014, 4, 38-45.

B. Subash, B. Krishnakumar, M. Swaminathan, and M. Shanthi, Langmuir., 2013, 29, 939−949.

Gusfiyesi, Admin Alif, Hermansyah Aziz, Syukri Arief and Edison Munaf. Res. J. Pharm. Biol. Chem. Sci., 2014, 5, 918.

Q. Xiang, Jiaguo Yu and Mietek Jaroniec, Phys. Chem. Chem. Phys., 2011, 13, 4853- 4861 4853.

K.I. Ishibashi, A. Fujishima, T. Watanabe and K. Hashimoto, Electrochem. Commun., 2000. 2, 207-10. ( Received 17 February 2015; accepted 23 February 2015 ).

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