Acustical Studies of Interactions in the Binary Mixtures of Ethylmethyl Ketone (EMK) and N,N-Dimethylformamide (DMF) through Ultrasonic Measurements at Different Temperatures

Patial, Baljeet Singh

doi:10.18052/www.scipress.com/ILCPA.47.120

ILCPA > ILCPA Volume 47 > Acustical Studies of Interactions in the Binary...

< Back to Volume

Acustical Studies of Interactions in the Binary Mixtures of Ethylmethyl Ketone (EMK) and N,N-Dimethylformamide (DMF) through Ultrasonic Measurements at Different Temperatures

Full Text PDF

Abstract:

Ultrasonic velocities (u), densities (ρ) and viscosities (η) are measured in respect of ethylmethylketone (EMK) and N,N-dimethylformamide (DMF) over the entire composition at 298, 308and 318K. Attempt have been made to extract the information with respect to various kind of intermolecular interactions, such as H-bonding, dipole-dipole, solute –solvent, dispersion type interactions existing between these two components from the following acoustical parameter when examined as a function of solvent composition at different temperatures: adiabatic compressibility (β), specific acoustic impedance (Z), intermolecular free length (Lf), molar sound velocity (Rm), wada’s constant (W), viscous relaxation time (τ), free volume and internal pressure (πi).

Info:

Periodical:

International Letters of Chemistry, Physics and Astronomy (Volume 47)

Pages:

120-132

DOI:

https://doi.org/10.18052/www.scipress.com/ILCPA.47.120

Citation:

B. S. Patial, "Acustical Studies of Interactions in the Binary Mixtures of Ethylmethyl Ketone (EMK) and N,N-Dimethylformamide (DMF) through Ultrasonic Measurements at Different Temperatures", International Letters of Chemistry, Physics and Astronomy, Vol. 47, pp. 120-132, 2015

Online since:

February 2015

Authors:

Baljeet Singh Patial

Keywords:

Density, Different Temperatures, Ethylmethylketone (EMK), N,N-Dimethylformamide (DMF), Ultrasonic Velocity, Viscosity

Export:

RIS, BibTeX, Text

Distribution:

Open Access

This work is licensed under a
Creative Commons Attribution 4.0 International License

References:

Grigorev S.B., Manucharov S.Y. and Masnucharov S.A., Vysokomol Soedin, Ser B, (USSR), 28, (1986)150.

Hautman, P.H., Saeuberlich R. and Schlothauer K., (Germany), 25, (1984)985.

Jacobson B., Acta Chem. Scand, 5(1951)1214; 6(1952)1485;J. chem. Phys. 20(1952)927.

Ali A., Hyder S. and Nain A.K., Acoustic let. 21(1998)21;J. Mol. Liq. 79(1991)89; Indian J. Phys. B74(2000)63.

Kannappan V. and Jaya Santhi R, Indian J. Pure Appl. Phys., 43(2005)750.

Ali A., Nain A.K. and Kamil M, Thermochim Acta, 274(1986)209.

Kinginger J.B., Tannahill M.M., Greenberg M.S. and Popov A.I., J. Phys. Chem., 77(1973)2444.

Hill N.E. & Vanghan W.E., Dielectric properties and Molecular Behaviour. (Van Nostrand. New York), (1969)31.

Syal V.K. , Lal G., Bist P. & Chauhan S., J. Mol. Liq., 63(1995)317.

Syal V.K., Bajaj J.M., Chauhan S. & Chauhan M. S., J. Indian Chem. Soc., 69(1992)807.

Syal V.K., Patial B. S. & Chauhan S., Acoustics Letters, 23(7)(2000)137.

Syal V.K., Chauhan Anita & chauhan Suvarcha, J. Pure Appl. Ultrason. 27(2005)61-69.

Kumar G. Pavan, Babu Ch. Praveen, Samatha K., Jyosthna N., Showrilu K., International Letters of Chemistry, Physics and Astronomy 10(2014)25-37.

Eyring H. and Kincaid J.F.,J. Chem., 6(1928)620.

Syal V K, Chauhan S & Uma Kumari, Indian J. pure Appl. Phys., 43(2005)844.

Kumar R, S. Jayakumar & Kannappan, Indian J. pure Appl. Phys., 46(2008)169-175.

Erying H and Kincaid J.F.; J. Pure & Appl. Ultrason., 6(1938)620.

Ali Askar S.J.; Journal of Chemical and Pharmaceutical Research, 4(1)(2012)617-632.

Chauhan M.S., Sharma M, Gupta S., Kumar A. and Chauhan S.; Czech. Chem. Commun., 60(1995)43.

Peter Hauptmann, Ralph Sauberlich and Klaus Schlothauer Polymer, vol 25 (1984) 985.

Chauhan S., Syal V.K. and Chauhan M S, Indian J. Pure Appl. Phys. 33(1995) 92.

Tong Jie and Dong Yan-wu and Dong Tian-Kui, Chinese Science Bulletin. 34 (1989) 1262.

Chauhan M. S., Sharma K. C., Gupta S., Sharma M., and Chauhan S.; Acoustic Letters, 18(1995)233.

Syal V.K., Chauhan A. & Chauahn S.; J Pure And Appl Ultrason, 27(2005)192.

Chauhan S. Kuldeep K., Patial B.S.; Indian J Pure & App. Phys., 51(2013)531-541. ( Received 26 January 2015; accepted 08 February 2015 ).

Show More Hide

Cited By:

This article has no citations.