Excess Molar Volumes, Intermolecular Free Lengths, Adiabatic Compressibilities and Acoustic Impedance of Binary Mixtures of Anisole, Toluene and Ethylbenzene with Dioxane at Different Temperatures

Dahire, S.L.; Morey, Y.C.; Agrawal, P.S.

doi:10.18052/www.scipress.com/ILCPA.42.72

ILCPA > ILCPA Volume 42 > Excess Molar Volumes, Intermolecular Free Lengths,...

< Back to Volume

Excess Molar Volumes, Intermolecular Free Lengths, Adiabatic Compressibilities and Acoustic Impedance of Binary Mixtures of Anisole, Toluene and Ethylbenzene with Dioxane at Different Temperatures

Full Text PDF

Abstract:

The present study reports densities (ρ), viscosities (η) and ultrasonic speeds (U) of pure dioxane (DOX), anisole (ANS), toluene (TOL) and ethylbenzene (ETB) and their binary liquid mixtures over the entire composition range at 293, 298, 303, 308 and 313 K. From the experimental data excess molar volume (V_m^E), excess intermolecular free length (L_f^E), excess adiabatic compressibility (β^E) and excess acoustic impedance (Z^E) have been computed. The excess values were correlated using Redlitch-Kister polynomial equation to obtain their coefficients and standard deviations (σ). With increase in temperature, the binary mixture of DOX+ANS shows larger deviations in β^E, L_f^E and smaller deviations in Z^E, V_m^E. These results suggest that ANS has strong molecular interactions with DOX than ETB and TOL.

Info:

Periodical:

International Letters of Chemistry, Physics and Astronomy (Volume 42)

Pages:

72-83

DOI:

https://doi.org/10.18052/www.scipress.com/ILCPA.42.72

Citation:

S.L. Dahire et al., "Excess Molar Volumes, Intermolecular Free Lengths, Adiabatic Compressibilities and Acoustic Impedance of Binary Mixtures of Anisole, Toluene and Ethylbenzene with Dioxane at Different Temperatures", International Letters of Chemistry, Physics and Astronomy, Vol. 42, pp. 72-83, 2015

Online since:

December 2014

Authors:

S.L. Dahire, Y.C. Morey, P.S. Agrawal

Keywords:

Acoustical Properties, Binary Liquid Mixture, Dioxane, Excess Parameters, Redlich-Kister Polynomial Equation

Export:

RIS, BibTeX, Text

Distribution:

Open Access

This work is licensed under a
Creative Commons Attribution 4.0 International License

References:

Kumar H., Dipika, Int. J. Chem. Sci. Tech. 2 (2012) 1.

Singh J., Mohanty G. C., Acharya S., Int. J. Sci. Res. Publ. 2 (2012) 22.

Pund D. A., Int. J. Chem. Phy. Sci. 2 (2013) 1.

Dhondage S. S., Pandhurnekar C. P., S., Gharde K., J. Chem. Eng. Data 56 (2011) 3484.

Ali A., Nain A. K., Sharma V. K., Ahmad S., Acoust. Lett. 24 (2000) 9.

Rajaguru P., Jayaraj, Acoust. Lett. 13 (1990) 142.

Redlitch O., Kister A. T., Indus. Eng. Chem. 40 (1998) 345.

Nikam P. S., Jadhav M. C., Hasan M., Indian J. Pure Appl. Phys. 33 (1995) 398.

Roy M. N., Sinha B., Dakua V. K., J. Mol. Liq. 136 (2007) 128.

Ali A., Nabi F., J. Mol. Liq. 143 (2008) 141.

Bhuiyan M. M., Uddin M. H., J. Mol. Liq. 138 (2008) 139.

Mozo I., Gonzalez J. A., de la Fuente I. G., Cobos J. C., Riesco N., J. Mol. Liq. 140 (2008) 87.

Rathnam M. V., Mohite S., Kumar M. S., J. Chem. Eng. Data 54 (2009) 305.

Raj A. M., Reshmi L. B., Jothy V. B., Jayachandran M., Sanjeeviraja C., Fluid Phase Equilib. 281 (2009) 78.

Saxena C. M., Saxena A., Srivastava A. K., Shukla N. K., J. Am. Chem. Sci. 3 (2013) 468.

Azhagiri S., Jayakumar S., Padmanaban R., Gunasekaran S., Srinivasan S., J. Solution Chem., 38 (2009) 441.

Treszczanowicz A. J., Kiyohara O., Benson G. C., J. Chem. Thermodyn. 13 (1981) 253.

Gracia B., Alcalde R., Leal J. M., Matos J. S., J. Chem. Soc. Faraday Trans. 92 (1996) 3347.

Raghuwanshi P. B., Mahalle P. V., Sci. Revs. Chem. Commun. 4 (2014) 30.

Mehra R., Israni R., Indian J. Chem. Tech. 9 (2001) 341.

Parmanik R., Bagehi S., J. Indian Chem. Soc. 80 (2003) 335.

Arul G., Palaniappan L., Indian J. Pure Appl. Phys. 43 (2005) 755.

Rena A., Clara C., Ana, Gomaz marigliona., Horacio, N. Solimo., J. Chem. Eng. Data 51 (2006) 1473.

Becu L., Manneville S., Colin A., Phys. Rev. Lett. 76 (2006) 13. ( Received 14 November 2014; accepted 23 November 2014 ).

Show More Hide

Cited By:

[1] A. Nabi, C. Yau, C. Jesudason, "Investigation of molecular interactions in binary mixtures (dichloromethane + aliphatic alcohols) at T = (298.15 to 308.15) K: Experimental, ERAS analyses and COSMO-RS predictions", Journal of Molecular Liquids, Vol. 224, p. 551, 2016

DOI: https://doi.org/10.1016/j.molliq.2016.10.013