Subscribe to our Newsletter and get informed about new publication regulary and special discounts for subscribers!

ILCPA > Volume 4 > Electrochemical Reduction Potential Correlation of...
< Back to Volume

Electrochemical Reduction Potential Correlation of some Insect Antifeedant Potent 2-Phenothiazinyl Chalcones

Full Text PDF


A series containing twelve substituted styryl 2-phenothiazenyl ketones have been synthesized. The electrochemical potentials of carbonyl and vinyl groups were measured. These potentials are correlated with Hammett substituent constants, F and R parameters. From the results of statistical analyses, the effects of substituent on the group reduction potentials have been discussed. The insect antifeedant activities of these chalcones have been studied using 4th instar larvae Achoea Janata L with castor leaf discs.


International Letters of Chemistry, Physics and Astronomy (Volume 4)
K. Ranganathan et al., "Electrochemical Reduction Potential Correlation of some Insect Antifeedant Potent 2-Phenothiazinyl Chalcones", International Letters of Chemistry, Physics and Astronomy, Vol. 4, pp. 66-75, 2012
Online since:
Sep 2013

[1] Zuman P, Substituent Effects in Organic Polarography, Plenum Press, New-York. (1967).

[2] Boykin D W, Ash M L, Berin F L O, J. Org. Chem. 37(1) (1972) 106-110.

[3] Alston J A, Fry A J, Electrochim. Acta. 49(3) (2004) 455-459.

[4] Morealeda D, Abed D E, Pellissier H, Santelli M, J. Mol. Struct. (TheoChem). 760(1-3) (2006) 113-119.

[5] (a). Arulkumaran R, Vijayakumar S, Sundararajan R, Sakthinathan S P, Kamalakkannan D, Suresh R, Ranganathan K, Vanangamudi G, Thirunarayanan G, Int. Lett. Chem. Phys. Astro. 4 (2012).

DOI: 10.4067/s0717-97072013000200008

[6] Lahtchev K L, Batovska D I, Parushev St P, Ubiyvock V M, Sibirny A A, Eur. J. Med. Chem. 43(10) (2008) 2220-2228.

DOI: 10.1016/j.ejmech.2007.12.027

[7] El-Subbagh Hussein I, Abu-Zaid S M, Mahran M A, Badria Farid A, Al-Obaid A M, J. Med. Chem. 43 (2000) 2915-2920.

DOI: 10.1021/jm000038m

[8] Thirunarayanan G, Surya S, Srinivasan S, Vanangamudi G, Sathyendiran V, Spectrochim. Acta Part A. 75 (2010) 152-156.

[9] Deng J, Sanchez T and Lalith Q A M, Bioorg. Med. Chem. 15(14), (2007) 4985-5002.

[10] Lin Y M, Zhon Y, Flavin M T, Zhon M, Ne W, Chen F C, Bioorg. Med. Chem. 10(8) (2002) 2795-2802.

[11] Weber M W, Hunsaker L A, Abcouwer S F, Decker L M, Vander Jagat D L, Bioorg. Med. Chem. 13 (2005) 3811-3820.

[12] Arulkumaran R, Sundararajan R, Vanangamudi G, Subramanian M, Ravi K, Sathiyendiran V, Srinivasan S, Thirunarayanan G, IUP. J. Chem. 3(1) (2010) 82-98.

[13] Thirunarayanan G, Vanangamudi G, Spectrochim. Acta. 81A (2011) 390-396.

[14] Thirunarayanan G, J. Indian Chem. Soc. 85(4) (2008) 447-451.

[15] Ranganthan K, Arulkumaran K, Kamalakannan D, Vanangamudi G, Thirunarayanan G, Iup. J. Chem. 4(2) (2011) 60-70.

[16] Thirunarayanan G, Vanangamudi G, Sathiyendiran V, Ravi K, Indian J. Chem. 50B(4) (2011) 593-604.

[17] Thirunarayanan G, IUP. J. Chem. 5(1) (2012) 41-53.

[18] Swain C G, Lupton Jr E C, J. Am. Chem. Soc. 90(16) (1968) 4328-4337.

[19] Dethler V G, Chemical insect attractants and repellents, Blackistan, Philadeciphia, (1947).

[20] Thirunarayanan G, J. Saudhi Chem Soc., 2011, doi10. 1016/j. jscs. 2011. 12. 003.

Show More Hide