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International Letters of Chemistry, Physics and Astronomy
Volume 39


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Di-Stimuli Responsive Poly(N-Isopropylacrylamide-co-Diethylaminoethylmethacrylate) Copolymer: Synthesis, Characterization and Investigation of Aqueous Dispersion Properties

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We report on the synthesis, characterization and aqueous dispersion properties of well-defined double hydrophilic copolymer with pH- and thermo-responsive segments via atom transfer radical polymerization (ATRP). Poly(N-isopropylacrylamide-co-Diethylaminoethylmeth-acrylate), P(NIPAAm-co-DEAEMA), was prepared by ATRP using methyl-4-bromomethyl benzoate initiator. The product was characterized by proton-nuclear magnetic resonance (1H NMR) and attenuated total reflectance infrared (ATR-IR) spectroscopy. The multi-responsive switching between unimer and two types of micellar aggregates were characterized by temperature-dependent dynamic light scattering (DLS). Self-assembles into two types spherical aggregates in 1 mg/mL (0.0315 mM) aqueous solution, depending on solution pH and temperatures were widely investigated. The result shows two types of aggregate with large (280 nm) aggregate and variable sizes of small (17 nm, 25 nm, 45 nm) aggregates depending on temperature ranges from 26 to 40 °C at pH 4.


International Letters of Chemistry, Physics and Astronomy (Volume 39)
M. S. Islam and M. Ashaduzzaman, "Di-Stimuli Responsive Poly(N-Isopropylacrylamide-co-Diethylaminoethylmethacrylate) Copolymer: Synthesis, Characterization and Investigation of Aqueous Dispersion Properties", International Letters of Chemistry, Physics and Astronomy, Vol. 39, pp. 136-144, 2014
Online since:
Oct 2014

E.S. Gil, S.M. Hudson, Prog. Polym. Sci. 29 (2004) 1173.

X.Z. Zhang, X.D. Xu, S.X. Cheng, R.X. Zhuo, Soft Matter 4 (2008) 385.

H.K. Ju, S.Y. Kim, S.J. Kim, Y.M. Lee, J. Appl. Polym. Sci. 83 (2002) 1128.

C. D. Alarcon, S. Pennadam, C. Alexander, Chem. Soc. Rev. 34 (2005) 276-285.

D. Cunliffe, C. D. Alarcon, V. Peters, J. R. Smith, C. Alexander, Langmuir 19 (2003) 2888-2899.

J. Hoffmann, M.; Potner, D. Kuckling, W. Fischer, J. Sens. Actuators A 77 (1999) 139-144.

L. K. Ista, G. P. Lopez, J. Ind. Microbiol. Biotechnol. 20 (1998) 121-125.

S. J. Kim, S. J. Park, S. M. Lee, Y. M. Lee, H. C. Kim, S. I. Kim, J. Appl. Polym. Sci. 89 (2003) 890-894.

S. Y. Liu, S. P. Armes, Langmuir 19 (2003) 4432-4438.

M. A. Nandkumar, M. Yamato, A. Kushida, C. Konno, M. Hirose, A. Kikuchi, T. Okano, Biomaterials 23 (2002) 1121-1130.

J. Raula, J. Shan, M. Nuopponen, A. Niskanen, H. Jiang, E. I. Kauppinen, H. Tenhu, Langmuir 19 (2003) 3499-3504.

G. Riess, Prog. Polym. Sci. 28 (2003) 1107-1170.

J. Rodriguez-Hernandez, F. Checot, Y. Gnanou, S. Lecommandoux, Prog. Polym. Sci. 30 (2005) 691-724.

H. G. Schild, Prog. Polym. Sci. 17 (1992) 163-249.

D. W. Urry, Biopolymers 47 (1998) 167-178.

M. Yamato, M. Utsumi, A. Kushida, C. Konno, A. Kikuchi, T. Okano, Tissue Eng. 7 (2001) 473-480.

S. K. Yang, M. Weck, Macromolecules 41 (2008) 346-351.

H. Zhu, G. H. Deng, Y. M. Chen, Polymer 49 (2008) 405-411.

I. In, Y. H. La, S. M. Park, P. F. Nealey, P. Gopalan, Langmuir 22 (2006) 7855-7860.

C. Cheng, K. Qi, E. Khoshdel, K. L. Wooley, J. Am. Chem. Soc. 128 (2006) 6808-6809.

C. Feng, Z. Shen, L. N. Gu, S. Zhang, L. T. Li, G. L. Lu, X. Y. Huang, J. Polym. Sci. Part A: Polym. Chem. 46 (2008) 5638-5651.

L. H. He, Zhang Y. H., Ren L. X., Chen Y. M., Wei H., Wang D. J., Macromol. Chem. Phys. 207 (2006) 684-693.

S. Yamamoto, J. Pietrasik, K. Matyjaszewski, Macromolecules 40 (2007) 9348.

Z. P. Cheng, X. L. Zhu, G. D. Fu, E. T. Kang, K. G. Neoh, Macromolecules 38 (2005) 7187-7192.

Y. Shi, Z. F. Fu, W. T. Yang, J. Polym. Sci., Part A: Polym. Chem. 44 (2006) 2069-75.

Z. Caoa, W. Liu, P. Gao, K. Yao, H. Li, G. Wang, Polymer 46 (2005) 5268-5277.

S. Y. Liu, S. P. Armes, Angew. Chem., Int. Ed. 41 (2002) 1413-1416.

G. D. Poe, C. L. McCormick, J. Polym. Sci., Part A: Polym. Chem. 42 (2004) 2520-2533.

J. Rodriguez-Hernandez, S. Lecommandoux, J. Am. Chem. Soc. 127 (2005) 2026-(2027).

M. Ashaduzzaman, S. Kai, S. Uemura, M. Kunitake, Chem. Lett. 40 (2011) 165-167.

C. M. Schilli, M. F. Zhang, E. Rizzardo, S. H. Thang, Y. K. Chong, K. Edwards, G. Karlsson, A. H. E. Muller, Macromolecules 37 (2004) 7861-7866.

B. S. Sumerlin, A. B. Lowe, D. B. Thomas, A. J. Convertine, M. S. Donovan, C. L. McCormick, J. Polym. Sci., Part A: Polym. Chem. 42 (2004) 1724-1734.

Virtanen J., Arotcarena M., Heise B., Ishaya S., Laschewsky A., Tenhu H., Langmuir 18 (2002) 5360-5365.

J. V. M. Weaver, S. P. Armes, S. Y. Liu, Macromolecules 36 (2003) 9994-9998.

S. Forster, T. Plantenberg, Angew. Chem. Int. Ed. 41 (2002) 689-714.

A. Ramzi, M. Prager, D. Richter, V. Efstratiadis, N. Hadjichristidis, R. N. Young, J. B. Allgaier, Macromolecules 30 (1997) 7171-7182.

S. Pispas, N. Hadjichristidis, I. Potemkin, A. Khokhlov, Macromolecules 33 (2000) 1741-1746.

K. Sotiriou, A. Nannou, G. Velis, S. Pispas, Macromolecules 35 (2002) 4106-4112.

J. P. Yun, R. Faust, L. S. Szilagyi, S. Keki, M. Zsuga, Macromolecules 36 (2003) 1717-1723.

Y. L. Cai, C. Burguiere, S. P. Armes, Chem. Commun. (2004) 802-803. ( Received 20 September 2014; accepted 30 September 2014 ).

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