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International Letters of Chemistry, Physics and Astronomy
Volume 36

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Acoustical Studies of Some Synthesized Schiff Base Derivatives in Dimethylsulphoxide at 303.15 K, by Ultrasonic Velocity Measurement

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Abstract:

The density, viscosity and sound velocity of five Schiff bases (1-5) derivatives in DMSO solutions have been studied at 303.15 K over a wide range of concentration. From these experimental data, some acoustical parameters such as Molar volume (Vm), Specific Acoustic Impedance (Z), Adiabatic compressibility (βad), Intermolecular Free Length (Lf), Rao’s Constant (R), Molar compressibility (W), Relaxation time(τ), van der Waals constant (b), Relaxation strength (r), Relative association (RA), Isothermal compressibility ( ) , Isothermal expansion co-efficient (α) ,Free volume (Vf) and Internal pressure (πi) and Ultrasonic attenuation (α/f²) have been evaluated. A fairly good correlation between a given parameter and concentration is observed. The results are interpreted in terms of molecular interactions like solvent-solvent, solvent-solute and solute-solute interactions.

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Periodical:
International Letters of Chemistry, Physics and Astronomy (Volume 36)
Pages:
50-66
Citation:
C. Gopi and N. Santhi, "Acoustical Studies of Some Synthesized Schiff Base Derivatives in Dimethylsulphoxide at 303.15 K, by Ultrasonic Velocity Measurement", International Letters of Chemistry, Physics and Astronomy, Vol. 36, pp. 50-66, 2014
Online since:
Jul 2014
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