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International Letters of Chemistry, Physics and Astronomy
Volume 33
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Study of Uni-Univalent H<sup>+</sup>/K<sup>+</sup> and Uni-Bivalent H<sup>+</sup>/Mg<sup>2+</sup> Ion Exchange Reactions Using Nuclear Grade Resin Indion-223
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Study of Uni-Univalent H+/K+ and Uni-Bivalent H+/Mg2+ Ion Exchange Reactions Using Nuclear Grade Resin Indion-223

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Abstract:

In the present paper the uni-univalent and uni-bivalent ion exchange reactions were investigated using nuclear grade anion exchange resin Indion-223 in H+ form. For both H+/K+ uni-univalet ion exchange reactions and H+/Mg2+ uni-bivalet ion exchange reactions, the equilibrium constant K values increases from 0.01710 to 0.02374 and from 0.000177 to 0.000333 respectively as the reaction temperature rises from 35.0 °C to 45.0 °C. The increase in K values with temperature suggest endothermic ion exchange reactions having the enthalpy change values of 22.72 and 51.46 kJ/ mol respectively. The results of such studies will help in selection of suitable ion exchange resins in order to bring about efficient separation of different ionic species present in the waste water effluents released from nuclear as well as chemical process industries.

Info:

Periodical:
International Letters of Chemistry, Physics and Astronomy (Volume 33)
Pages:
231-239
DOI:
https://doi.org/10.18052/www.scipress.com/ILCPA.33.231
Citation:
P. U. Singare et al., "Study of Uni-Univalent H+/K+ and Uni-Bivalent H+/Mg2+ Ion Exchange Reactions Using Nuclear Grade Resin Indion-223", International Letters of Chemistry, Physics and Astronomy, Vol. 33, pp. 231-239, 2014
Online since:
May 2014
Authors:
Pravin U. Singare, Akmal L. Khan Mohammed, N.N. Dixit
Keywords:
Cation Exchange, Enthalpy Change, Equilibrium Constant, Indion-223, Ion Exchange Equilibrium, Nuclear Grade Resin
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Distribution:
Open Access

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This work is licensed under a
Creative Commons Attribution 4.0 International License

References:

M. Marhol, Comprehensive Analytical Chemistry XIV, Ion Exchangers (1982) 117-160.

Ion Exchange Technology I-Theory and Materials, Inamuddin, M. Luqman (Eds. ), ISBN 978-94-007-1700-8(eBook), DOI 10. 1007/978-94-007-1700-8, Springer Dordrecht Heidelberg New York, London, (2012).

Application of Ion Exchange Processes For the Treatment of Radioactive Waste and Management of Spent Ion Exchangers, Technical Reports Series No. 408, International Atomic Energy Agency, Vienna, (2002).

S.K. Samanta, M. Ramaswamy, B.M. Misra, Sep. Sci. Technol. 27 (1992) 255-267.

S.K. Samanta, M. Ramaswamy, P. Sen, N. Varadarajan, R.K. Singh, Removal of Radiocesium from alkaline IL waste, Natl Symp. On Management of Radioactive and Toxic Wastes (SMART-93), Kalpakkam, 1993, Bhabha Atomic Research Centre, Bombay, 1993, 56-58.

S.K. Samanta, T.K. Theyyunni, B.M. Misra, J. Nucl. Sci. Technol. 32 (1995) 425-429.

Y. Kulkarni, S.K. Samanta, S.Y. Bakre, K. Raj, M.S. Kumra, Process for treatment of intermediate level radioactive waste based on radionuclide separation, Waste Management' 96, (Proc. Int. Symp. Tucson, AZ, 1996), Arizona Board of Regents, Phoenix, AZ (1996).

L.A. Bray, R.J. Elovich, K.J. Carson, Cesium Recovery using Savannah River Laboratory Resorcinol-formaldehyde Ion Exchange Resin, Rep. PNL-7273, Pacific Northwest Lab., Richland, WA (1990).

P.U. Singare, R.S. Lokhande, V.V. Patil, T. S. Prabhavalkar , S. R. D. Tiwari, European Journal of Chemistry 1(1) (2010) 47-49.

P.U. Singare, R.S. Lokhande, P. Karthekayan, S.R.D. Tiwari, Colloid Journal 72(06) (2010) 874-876.

P.U. Singare, R.S. Lokhande, A.R. Kolte, International Journal of Nuclear Desalination 3(4) (2009) 383-389.

P.U. Singare, R.S. Lokhande, S.A. Parab, A.B. Patil, International Journal of Nuclear Desalination 3(4) (2009) 375-382.

Adachi S., Mizuno T., Matsuno R., J. Chromatogr. A 708 (1995) 177-183.

Shuji A., Takcshi M., Ryuichi M., Biosci. Biotechnol. Biochem. 60(2) (1996) 338-340.

P.U. Singare, Journal of Analytical Science and Technology 5 (2014) 30.

P.U. Singare, Kerntechnik 79(1) (2014) 51-57.

P.U. Singare, Diffusion Fundamentals Online Journal 19(4) (2013) 1-21.

P.U. Singare, Journal of Radioanalytical and Nuclear Chemistry 299 (2014) 591-598.

P.U. Singare, International Journal of Nuclear Energy Science and Technology 8(2) (2014) 157-170.

P.U. Singare, Nuclear Engineering and Technology 46(1) (2014) 93-100.

P.U. Singare, Colloid Journal 76(2) (2014) 193-201.

P.U. Singare, J. Nuclear Energy Science & Power Generation Technology 2(2) (2013) 1-6.

P. U. Singare, International Letters of Chemistry, Physics and Astronomy 13 (2013) 37-49.

P. U. Singare, International Letters of Chemistry, Physics and Astronomy 13 (2013) 50-62.

P. U. Singare, International Letters of Chemistry, Physics and Astronomy 13 (2013) 63-76.

P. U. Singare, International Letters of Chemistry, Physics and Astronomy 13 (2013) 77-89.

P. U. Singare, International Letters of Chemistry, Physics and Astronomy 12 (2013) 1-13.

P. U. Singare, International Letters of Chemistry, Physics and Astronomy 12 (2013) 14-27.

P.U. Singare, International Letters of Chemistry, Physics and Astronomy 6 (2013) 1-5.

P.U. Singare, R.S. Lokhande, Ionics 18(4) (2012) 351-357.

P.U. Singare, Journal of Modern Chemistry & Chemical Technology 5(1) (2014) 34-44.

P.U. Singare, Journal of Nuclear Engineering & Technology 4(1) (2014) 13-24.

P.U. Singare, Journal of Nuclear Engineering & Technology 4(1) (2014) 1-12.

P.U. Singare, Journal of Nuclear Engineering & Technology 3(3) (2013) 1-11.

P.U. Singare, Journal of Nuclear Engineering &Technology 3(2) (2013) 14-24.

R. N. Singru, Archives of Applied Science Research, 3 (5): 309-325 (2011).

R. N. Singru, ISRN Thermodynamics, 2012 (2012), Article ID 323916, 8 pages.

Y. H. Ju, O. F. Webb, S. Dai, J. S. Lin, C. E. Barnes, Ind. Eng. Chem. Res. 39 (2) (2000) 550-553.

N.N. Andreev, Yu.I. Kuznetsov, Russ. J. Phys. Chem. 64 (1990) 1537.

A. Bhargava, C. Janardanan, Indian J. Chem., 36A (1997) 624.

D. Muraviev, A. Gonzalo, M. Valiente, Anal. Chem. 67 (1995) 3028.

G.E. Boyd, F. Vaslow, S. Lindenbaum, J. Phys. Chem. 71 (1967) 2214.

J.F. Duncan, Aus. J. Chem. Soc. 8 (1955) 1.

G.E. Boyd, F. Vaslow, S. Lindenbaum, J. Phys. Chem. 68 (1964) 590.

A. Schwarz, G.E. Boyd, J. Phys. Chem. 69 (1965) 4268.

N.I. Gamayunov, Russ. J. Phys. Chem. 64 (1990) 1787.

G.E. Boyd, G.E. Myers, J. Phys. Chem. 60 (1956) 521.

O.D. Bonner, J. Phys. Chem. 59 (1955) 719.

O.D. Bonner, J. Phys. Chem. 58 (1954) 318.

S. Lindenbaum, C.F. Jumper, G.E. Boyd, J. Phys. Chem. 63 (1959) (1924).

K.A. Kraus, R.J. Raridon, J. Phys. Chem. 63 91959) (1901).

O.D. Bonner, W.H. Payne, J. Phys. Chem. 58 (1954) 18.

W.J. Argersinger, A.W. Davidson, J. Phys. Chem. 56 (1952) 92.

O.D. Bonner, R.R. Pruett, J. Phys. Chem. 63 (1959) 1420.

O.D. Bonner, F.L. Livingston, J. Phys. Chem. 60 (1959) 530.

O.D. Bonner, L.L. Smith, J. Phys. Chem. 61 (1957) 326.

O.D. Bonner, C.F. Jumper, O.C. Rogers, J. Phys. Chem. 62 (1958) 250.

O.D. Bonner, L.L. Smith, J. Phys. Chem. 61 (1957) 1614.

J. Kielland, J. Soc. Chem. Ind. 54 (1935) 232.

A.P. Vanselow, J. Am. Chem. Soc. 54 (1932) 1307.

G.L. Gaines (Jr. ), H.C. Thomas, J. Chem. Phys. 21 (1953) 714.

K.A. Kraus, R.J. Raridon, D.L. Holcomb, Chromatogr. J. (1960, 3178.

R.S. Lokhande, P.U. Singare, A.B. Patil, Russ. J. Phys. Chem. A 81 (2007) (2059).

P.U. Singare, R.S. Lokhande, T.S. Prabhavalkar, Bull. Chem. Soc. Ethiop. 22 (2008) 415.

R.S. Lokhande, P. U. Singare, Journal of Indian Council of Chemists 24 (2007) 73.

R.S. Lokhande, P.U. Singare, A.R. Kolte, Bull. Chem. Soc. Ethiop. 22 (2008) 107.

K.G. Heumann, K. Baier, Chromatographia 15 (1982) 701.

O.D. Bonner, G. Dickel, H. Brummer, Z. Physik. Chem. 25 (1960) 81.

G.L. Starobinet, V.S. Soldatov, A.A. Krylova, Russ. J. Phys. Chem. 41 (1967) 194.

P.U. Singare, A.N. Patange, International Letters of Chemistry, Physics and Astronomy 11(1) (2014) 67-73.

P.U. Singare, A.N. Patange, International Letters of Chemistry, Physics and Astronomy 11(1) (2014) 44-50.

P. U. Singare, A. N. Patange, International Letters of Chemistry, Physics and Astronomy 6 (2014) 8-15.

P. U. Singare, A. N. Patange, International Letters of Chemistry, Physics and Astronomy 6 2014) 1-7. ( Received 02 May 2014; accepted 09 May 2014 ).

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