Thermodynamics of Uni-Univalent H+/K+ and Uni-Bivalent H+/Ca2+ Ion Exchange Reactions Using Nuclear Grade Resin Indion-223

Singare, Pravin U.; Mohammed, Akmal L. Khan; Dixit, N.N.

doi:10.18052/www.scipress.com/ILCPA.33.190

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Thermodynamics of Uni-Univalent H⁺/K⁺ and Uni-Bivalent H⁺/Ca²⁺ Ion Exchange Reactions Using Nuclear Grade Resin Indion-223

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Abstract:

The present paper deals with the thermodynamic of uni-univalent and uni-bivalent ion exchange reactions using nuclear grade anion exchange resin Indion-223. It was observed that with rise in temperature the equilibrium constants K values for H⁺/K⁺ uni-univalet ion exchange reaction increases from 0.01710 to 0.02374. Similarly for H⁺/Ca²⁺ uni-bivalet ion exchange reaction the equilibrium constants K values increases from 0.000397 to 0.000639. The increase in K values with rise in temperature for both the reactions indicates its endothermic nature having the enthalpy change values of 22.72 and 38.92 kJ/ mol respectively. The technique used here can be extended further to standardise the process parameters in order to bring about the efficient separation of the desired ionic species from the solution

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Periodical:

International Letters of Chemistry, Physics and Astronomy (Volume 33)

Pages:

190-198

DOI:

https://doi.org/10.18052/www.scipress.com/ILCPA.33.190

Citation:

P. U. Singare et al., "Thermodynamics of Uni-Univalent H⁺/K⁺ and Uni-Bivalent H⁺/Ca²⁺ Ion Exchange Reactions Using Nuclear Grade Resin Indion-223", International Letters of Chemistry, Physics and Astronomy, Vol. 33, pp. 190-198, 2014

Online since:

May 2014

Authors:

Pravin U. Singare, Akmal L. Khan Mohammed, N.N. Dixit

Keywords:

Cation Exchangers, Enthalpy Change, Indion-223, Ion-Exchange, Nuclear Grade Resin, Standard Equilibrium Constant

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Open Access

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Creative Commons Attribution 4.0 International License

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