Thermodynamics of Uni-Univalent H+/K+ and Uni-Bivalent H+/Ca2+ Ion Exchange Reactions Using Nuclear Grade Resin Indion-223

Singare, Pravin U.; Mohammed, Akmal L. Khan; Dixit, N.N.

doi:10.18052/www.scipress.com/ILCPA.33.190

ILCPA > ILCPA Volume 33 > Thermodynamics of Uni-Univalent H+/K+ and...

< Back to Volume

Thermodynamics of Uni-Univalent H⁺/K⁺ and Uni-Bivalent H⁺/Ca²⁺ Ion Exchange Reactions Using Nuclear Grade Resin Indion-223

Full Text PDF

Abstract:

The present paper deals with the thermodynamic of uni-univalent and uni-bivalent ion exchange reactions using nuclear grade anion exchange resin Indion-223. It was observed that with rise in temperature the equilibrium constants K values for H⁺/K⁺ uni-univalet ion exchange reaction increases from 0.01710 to 0.02374. Similarly for H⁺/Ca²⁺ uni-bivalet ion exchange reaction the equilibrium constants K values increases from 0.000397 to 0.000639. The increase in K values with rise in temperature for both the reactions indicates its endothermic nature having the enthalpy change values of 22.72 and 38.92 kJ/ mol respectively. The technique used here can be extended further to standardise the process parameters in order to bring about the efficient separation of the desired ionic species from the solution

Info:

Periodical:

International Letters of Chemistry, Physics and Astronomy (Volume 33)

Pages:

190-198

DOI:

https://doi.org/10.18052/www.scipress.com/ILCPA.33.190

Citation:

P. U. Singare et al., "Thermodynamics of Uni-Univalent H⁺/K⁺ and Uni-Bivalent H⁺/Ca²⁺ Ion Exchange Reactions Using Nuclear Grade Resin Indion-223", International Letters of Chemistry, Physics and Astronomy, Vol. 33, pp. 190-198, 2014

Online since:

May 2014

Authors:

Pravin U. Singare, Akmal L. Khan Mohammed, N.N. Dixit

Keywords:

Cation Exchangers, Enthalpy Change, Indion-223, Ion-Exchange, Nuclear Grade Resin, Standard Equilibrium Constant

Export:

RIS, BibTeX, Text

Distribution:

Open Access

This work is licensed under a
Creative Commons Attribution 4.0 International License

References:

S.K. Samanta, M. Ramaswamy, B.M. Misra, Sep. Sci. Technol. 27 (1992) 255-267.

S.K. Samanta, M. Ramaswamy, P. Sen, N. Varadarajan, R.K. Singh, Removal of Radiocesium from alkaline IL waste, Natl Symp. On Management of Radioactive and Toxic Wastes (SMART-93), Kalpakkam, 1993, Bhabha Atomic Research Centre, Bombay, 1993, 56-58.

S.K. Samanta, T.K. Theyyunni, B.M. Misra, J. Nucl. Sci. Technol. 32 (1995) 425-429.

Y. Kulkarni, S.K. Samanta, S.Y. Bakre, K. Raj, M.S. Kumra, Process for treatment of intermediate level radioactive waste based on radionuclide separation, Waste Management' 96, (Proc. Int. Symp. Tucson, AZ, 1996), Arizona Board of Regents, Phoenix, AZ (1996).

L.A. Bray, R.J. Elovich, K.J. Carson, Cesium Recovery using Savannah River Laboratory Resorcinol-formaldehyde Ion Exchange Resin, Rep. PNL-7273, Pacific Northwest Lab., Richland, WA (1990).

L. Zhu, Y. Liu, J. Chen, Ind. Eng. Chem. Res. 48(7) (2009) 3261-3267.

S.A.R. Zaidi, G.B. Shah, Macromolecular Chemistry and Physics 201(18) (2000) 2760-2764.

International Atomic Energy Agency, Treatment of Low and Intermediate Level Liquid Radioactive Wastes, Technical Reports Series No. 236, IAEA, Vienna (1984).

International Atomic Energy Agency, Advances in Technologies for the Treatment of Low and Intermediate Level Radioactive Liquid Wastes, Technical Reports Series No. 370, IAEA, Vienna (1994).

P.U. Singare, A.N. Patange, International Letters of Chemistry, Physics and Astronomy 11(1) (2014) 67-73.

P.U. Singare, A.N. Patange, International Letters of Chemistry, Physics and Astronomy 11(10 (2014) 44-50.

P. U. Singare, A. N. Patange, International Letters of Chemistry, Physics and Astronomy 6 (2014) 8-15.

P. U. Singare, A. N. Patange, International Letters of Chemistry, Physics and Astronomy 6 (2014) 1-7.

P.U. Singare, R.S. Lokhande, R.S. Madyal, Open Journal of Physical Chemistry 1(2) (2011) 45-54.

P.U. Singare, R.S. Lokhande, R.S. Madyal, Rus. J. Gen. Chem. 80(3) (2010) 527-532.

R.S. Lokhande, P.U. Singare, S.R.D. Tiwari, Russ.J. Gen. Chem. 80(10) (2010) 2054-2058 (2010).

P.U. Singare, R.S. Lokhande , N.G. Samant , M.R. Dhatrak, Colloid Journal 72(4) (2010) 538-543.

P.U. Singare, R.S. Lokhande, N. Samant, Natural Science 1(2) (2009) 124-128.

R.S. Lokhande, P.U. Singare, M.H. Dole, Russ. J. Physical Chemistry 83(13) (2009) 2313-2317.

P.U. Singare, R.S. Lokhande, T.S. Prabhavalkar, Bull. Chem. Soc. Ethiop. 22(3) (2008) 415-421.

R.S. Lokhande, P.U. Singare, A.R. Kolte, Bull. Chem. Soc. Ethiop. 22(1) (2008) 107-114 (2008).

R. S. Lokhande, P. U. Singare, A. B. Patil, Russ. J. Physical Chemistry A 81(12) (2007) 2059-(2063).

P.U. Singare, R.S. Lokhande, M.B. Nadar, Oriental Journal of Chemistry 25(4) (2009) 879-883.

P.U. Singare, R.S. Lokhande, M.B. Nadar, Oriental Journal of Chemistry 25(3) (2009) 755-758 (2009).

P.U. Singare, R.S. Lokhande, M.B. Nadar, Oriental Journal of Chemistry 25(3) (2009) 587-592 (2009).

P.U. Singare, R.S. Lokhande, M.R. Dhatrak, M.D. Karad, Oriental Journal of Chemistry 25(3) (2009) 687-693.

P.U. Singare, R.S. Lokhande, Rochelle D'Souza, Rasāyan J. Chemistry 2(2) 507-511.

P.U. Singare, R.S. Lokhande, Rochelle D'Souza, Rasāyan J. Chemistry 2(4) (2009) 941-945.

P.U. Singare, R.S. Lokhande, Rochelle D'Souza, Rasāyan J. Chemistry 2(3) (2009) 645-648.

P.U. Singare, R.S. Lokhande, S.Y. Pimple, Rasāyan J. Chemistry 2(1) (2009) 75-80.

P.U. Singare, R.S. Lokhande, S.Y. Pimple, Rasāyan Journal of Chemistry 2(2) (2009) 315-321.

P.U. Singare, R.S. Lokhande, S.Y. Pimple, Rasāyan Journal of Chemistry 2(3) (2009) 617-621.

P.U. Singare, R.S. Lokhande, P.C. Vartak, Rasāyan J. Chemistry 2(1) (2009) 96-100.

P.U. Singare, R.S. Lokhande, P.C. Vartak, Rasāyan Journal of Chemistry 2(2) (2009) 491-496.

P.U. Singare, R.S. Lokhande, P.C. Vartak, Rasāyan Journal of Chemistry 2(4) (2009) 807-812.

P.U. Singare, R.S. Lokhande, M.G. Patil, Rasāyan J. Chemistry 2(1) (2009) 114-119.

P.U. Singare, R.S. Lokhande, M.G. Patil, Rasāyan Journal of Chemistry 2(3) (2009) 566-571.

P.U. Singare, R.S. Lokhande, M.G. Patil, Rasāyan Journal of Chemistry 2(4) (2009) 861-864.

P.U. Singare, R.S. Lokhande, N.P. Vanmali, Rasāyan Journal of Chemistry 2(2) (2009) 280-284.

P.U. Singare, R.S. Lokhande, N.P. Vanmali, Rasāyan Journal of Chemistry 2(3) (2009) 593-597.

P.U. Singare, R.S. Lokhande, N.P. Vanmali, Rasāyan Journal of Chemistry 2(4) (2009) 901-906.

P.U. Singare, R.S. Lokhande, V.Y. Pattebahadur, Int. J. Chem. Sci. 7(2) (2009) 797-804.

P.U. Singare, R.S. Lokhande, V.Y. Pattebahadur, Int. J. Chem. Sci. 7(2) (2009) 722-730.

P.U. Singare, R.S. Lokhande, V.Y. Pattebahadur, Int. J. Chem. Sci. 7(2) (2009) 1472-1478.

P.U. Singare, R.S. Lokhande, A.R. Kolte, M.H. Dole, P. Karthikeyan, S.A. Parab, Int. J. Chem. Sci. 6(4) (2008) 2172-2181.

R.S. Lokhande, P.U. Singare, P. Karthikeyan, J. Indian Council of Chemists 25(2) (2008) 117-121.

R.S. Lokhande, P.U. Singare, J. Indian Council of Chemists 24(02) (2007) 73-77.

P. U. Singare, International Letters of Chemistry, Physics and Astronomy 13 (2013) 37-49.

P. U. Singare, International Letters of Chemistry, Physics and Astronomy 13 (2013) 50-62.

P. U. Singare, International Letters of Chemistry, Physics and Astronomy 13 (2013) 63-76.

P. U. Singare, International Letters of Chemistry, Physics and Astronomy 13 (2013) 77-89.

P. U. Singare, International Letters of Chemistry, Physics and Astronomy 12 (2013) 1-13.

P. U. Singare, International Letters of Chemistry, Physics and Astronomy 12 (2013) 14-27.

P.U. Singare, International Letters of Chemistry, Physics and Astronomy 6 (2013) 1-5. ( Received 02 May 2014; accepted 09 May 2014 ).

Show More Hide

Cited By:

This article has no citations.