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International Letters of Chemistry, Physics and Astronomy
Volume 30
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Study on Halide Ions Selectivity of Nuclear Grade Anion Exchange Resin Auchlite ARA-9366

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Abstract:

The selectivity behaviour of nuclear grade anion exchange resin Auchlite ARA-9366 in chloride form towards iodide and bromide ions in the solution was studied. The trend in selectivity of the resin was predicted on the basis of thermodynamics of Clˉ/Iˉ and Clˉ/Brˉ uni-univalent ion exchange reactions. It was observed that the equilibrium constants K values for Clˉ/Iˉ ion exchange reaction were higher than that calculated for Clˉ/Brˉ exchange under identical experimental conditions. Also the enthalpy values for the two uni-univalent ion exchange reactions were calculated as -47.87 and -36.14 kJ/mol respectively. The high K and low enthalpy values obtained for Clˉ/Iˉ ion exchange reaction as compared to that obtained during Clˉ/Brˉ exchange supports higher selectivity of the resin towards iodide ions as compared to that towards bromide ions, when both the ions are present in the same solution.

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Periodical:
International Letters of Chemistry, Physics and Astronomy (Volume 30)
Pages:
67-73
Citation:
P.U. Singare and A.N. Patange, "Study on Halide Ions Selectivity of Nuclear Grade Anion Exchange Resin Auchlite ARA-9366", International Letters of Chemistry, Physics and Astronomy, Vol. 30, pp. 67-73, 2014
Online since:
March 2014
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[1] Marhol, M., Comprehensive Analytical Chemistry, Ion Exchangers, XIV (1982) 117-160.

[2] Samanta, S.K., Ramaswamy, M., Misra, B.M., Sep. Sci. Technol. 27 (1992) 255-267.

[3] Samanta, S.K., Ramaswamy, M., Sen, P., Varadarajan, N., Singh, R.K., Removal of radiocesium from alkaline IL waste, Natl Symp. On Management of Radioactive and Toxic Wastes (SMART-93), Kalpakkam, 1993, Bhabha Atomic Research Centre, Bombay, 1993, 56-58.

[4] Samanta, S.K., Theyyunni, T.K., Misra, B.M., J. Nucl. Sci. Technol. 32 (1995) 425-429.

[5] Kulkarni, Y., Samanta, S.K., Bakre, S.Y., Raj, K., Kumra, M.S., Process for treatment of intermediate level radioactive waste based on radionuclide separation, Waste Management'96 (Proc. Int. Symp Tucson, AZ, 1996), Arizona Board of Regents, Phoenix, AZ (1996).

[6] Bray, L.A., Elovich, R.J., Carson, K.J., Cesium Recovery using Savannah River Laboratory Resorcinol-formaldehyde Ion Exchange Resin, Rep. PNL- 7273, Pacific Northwest Lab., Richland, WA (1990).

DOI: https://doi.org/10.2172/7110253

[7] Singare, P.U., Lokhande, R.S., Madyal, R.S., Open Journal of Physical Chemistry 1(2) (2011) 45-54.

[8] Singare, P.U., Lokhande, R.S., Madyal, R.S., Rus. J. Gen. Chem. 80(3) (2010) 527-532.

[9] Tomoi, M., Yamaguchi, K., Ando, R., Kantake, Y., Aosaki, Y., Kubota, H., J. Appl. Poly. Sci. 64(6) (1997) 1161-1167.

[10] Zhu, L., Liu, Y., Chen, J., Ind. Eng. Chem. Res. 48(7) (2009) 3261-3267.

[11] Kumaresan, R., Sabharwal, K. N., Srinivasan, T. G., Vasudeva Rao, P.R., Dhekane, G., Solvent Extraction and Ion Exchange 24(4) (2006) 589-602.

DOI: https://doi.org/10.1080/07366290600762512

[12] Cortina, J. L., Warshawsky, A., Kahana, N., Kampel, V., Sampaio, C. H., Kautzman, R.M., Reactive and Functional Polymers 54(1-3) (2003) 25-35.

[13] Zaidi, S.A.R., Shah, G.B., Macromolecular chemistry and physics 201(18) (2000) 2760-2764.

[14] Sugii, A., Ogawa, N., Nozaki, Y., Haratake, M., Reactive Polymers, Ion Exchangers, Sorbents, 8(1) (1988) 3-6.

[15] Yergozhin, Ye. Ye., Abdrakhmanova, I.K., Menligaziyev, Ye. Zh., Polymer Science U.S.S.R. 23(11) (1981) 2671-2678.

DOI: https://doi.org/10.1016/0032-3950(81)90039-3

[16] Ion Exchange Technology I-Theory and Materials, Inamuddin, M. Luqman (Eds. ), ISBN 978-94-007-1700-8 (eBook), DOI 10. 1007/978-94-007-1700-8, Springer Dordrecht Heidelberg New York, London, (2012).

DOI: https://doi.org/10.1111/maec.12276

[17] Jeffery, G. H., Basset, J., Mendham, J., Denney, R. C., Ion Exchange, in Vogel's Textbook of Quantitative Chemical Analysis, 5th Ed., ELBS, Longman Scientific and Technical, England, (1989) p.208.

[18] Singare, P.U., Diffusion Fundamentals Online Journal 19(4) (2013) 1-21.

[19] Singare, P.U., Int. J. Nucl. Energy Sci. and Technol. 8(2) (2014) 157-170.

[20] Singare, P.U., J. Nucl. Energy Science and Power Generation Technology 2(2) (2013) 1-6.

[21] Singare, P.U., International Letters of Chemistry, Physics and Astronomy 13 (2013) 37-49.

[22] Singare, P.U., International Letters of Chemistry, Physics and Astronomy 13 (2013) 50-62.

[23] Singare, P.U., International Letters of Chemistry, Physics and Astronomy 13 (2013) 63-76.

[24] Singare, P.U., International Letters of Chemistry, Physics and Astronomy 13 (2013) 77-89.

[25] Singare, P.U., International Letters of Chemistry, Physics and Astronomy 12 (2013) 1-13.

[26] Singare, P.U., International Letters of Chemistry, Physics and Astronomy 12 (2013) 14-27.

[27] Singare, P.U., International Letters of Chemistry, Physics and Astronomy 6 (2013) 1-5.

[28] P. U. Singare, A. N. Patange, International Letters of Chemistry, Physics and Astronomy 6 (2014) 1-7.

[29] P.U. Singare, A.N. Patange, International Letters of Chemistry, Physics and Astronomy 6 (2014) 8-15.

[30] Singare, P.U., Inter. J. Materials and Chemistry 2(4) (2012) 151-157.

[31] Singare, P.U., Phys. Chem. 2(4) (2012) 48-55.

[32] Singare, P.U., Science and Technology 2(5) (2012) 135-141.

[33] Singare, P.U., American J. Fluid Dynamics 2(5) (2012) 71-77.

[34] Singare, P.U., American J. Chem. 2(5) (2012) 263-270.

[35] Singare, P.U., Int. J. Composite Materials 2(6) (2012) 119-126.

[36] Singare, P.U., J. Nuclear and Particle Physics 2(5) (2012) 119-125.

[37] Singare, P.U., Frontiers in Science 2(6) (2012) 235-242.

[38] Singare, P.U., Advances in Anal. Chem. 2(5) (2012) 53-59.

[39] Singare, P.U., American J. Poly. Sci. 2(5) (2012) 115-121.

[40] Singare, P.U., Phys. Chem. 2(3) (2012) 37-42.

[41] Singare, P.U., Journal of Radioanalytical and Nuclear Chemistry 299 (2014) 591-598.

[42] Singare, P.U., Nuclear Engineering and Technology, 46(1), 93-100 (2014).

[43] Singare, P.U., Journal of Nuclear Engineering & Technology 4(1) (2014) 13-24.

[44] Singare, P.U., Journal of Nuclear Engineering & Technology 4(1) (2014) 1-12.

[45] Singare, P.U., Journal of Nuclear Engineering & Technology 3(2) (2013) 14-24.

[46] Singare, P.U., Journal of Nuclear Engineering & Technology 3(3) (2013) 1-11.

[47] Bonner, O.D., Pruett, R.R., J. Phys. Chem. 63 (1959) 1420. ( Received 01 March 2014; accepted 06 March 2014 ).

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