Subscribe to our Newsletter and get informed about new publication regulary and special discounts for subscribers!

ILCPA > Volume 23 > Extractive Spectrophotometric Determination of...
< Back to Volume

Extractive Spectrophotometric Determination of Pd(II) with Sodium Salt of Hexamethyleneiminecarbodithioate

Full Text PDF


The reagent NaHMICdt·2H2O has found to be a good chelating agent for the spectrophotometric determination of various metal ions. The present investigation deals with spectrophotometric determination of Pd(II) by using NaHMICdt·2H2O. The reagent reacted with Pd(II) to give yellow complex extractable into toluene. Pd (II) was extracted quantitatively in the pH range 0.5-2.0. Pd(II)-HMICdt complex showed λmax at 435 nm. The extracted species has a 1:2 (M:L) stoicheometry. Beer’s law is obeyed in the range of 0.2-0.8 μg ml-1 of Pd (II). The molar absorptivity and the sandells sensitivity were found to be 0.754 x 104 lmol-1cm-1 and 0.0140 μg mol-1 cm-2 respectively. The effect of divers ion on the extraction of Pd(II) has been investigated. The proposed method is highly sensitive, selective, and simple and rapid has been applied for accurate determination of palladium in synthesis mixtures and real samples.


International Letters of Chemistry, Physics and Astronomy (Volume 23)
S.D. Dhanavate et al., "Extractive Spectrophotometric Determination of Pd(II) with Sodium Salt of Hexamethyleneiminecarbodithioate", International Letters of Chemistry, Physics and Astronomy, Vol. 23, pp. 20-28, 2014
Online since:
Nov 2013

Singhal G., Bhavesh R., Kasariya K., Sharma A., Singh R., J Nanopart Res 13 (2011) 2981-2988.

Cadete Santos Aires F. J., Kurzina I., Garcia Cervantes G., Bertolini J. C., Catal Today 117 (2006) 518-524.

Moreno-Alvarez S. A., Martinez-Castanon G. A., Nino-Martinez N., Reyes-Macias J. F., Patino-Marin N., Loyola-Rodriguez J. P., Ruiz F., J Nanopart Res 12 (2010) 2741-2746.

Iwase A., Kato H., Kudo A., Catal Lett. 108 (2006) 7-10.

Nagy G., Hancsok J., Varga Z., Polczmann G., Kallo D., Top Catal. 45 (2007) 195-201.

Chassary P., Vincent T., Marcano J. S., Macaskie L. E., Guibal E., Hydrometallurgy 76 (2005) 131-147.

Barakat M. A., Mahmoud M. H. H., Hydrometallurgy 72 (2004) 179-184.

Kramer J., Driessen W. L., Koch K. R., Reedijk J., Hydrometallurgy 64 (2002) 59-68.

Rane M. V., Venugopal V., Hydrometallurgy 84 (2006) 54-59.

Mhaske A. A., Dhadke P. M., Hydrometallurgy 61 (2001) 143-150.

Kanetake T., Otomo M., Anal Sci. 4 (1988) 411-416.

Sinha S. H., Sawant A. D., Bull Chem Soc Jpn. 65 (1992) 1622-1625.

Nakanishi T., Otomo M., Anal Sci. 1 (1985) 161-164.

Desai B. J., Shinde V. M., Fresenius Z Anal Chem. 295 (1979) 412-413.

Kumar A., Gautam M., Puri B. K., Microchem. J. 33 (1986) 256-263.

Sarma L. S., Kumar J. R., Reddy K. J., Kumar A. K., Reddy A. V., Anal Sci. 18 (2002) 1257-1261.

Narayana S. L., Reddy K. J., Reddy S. A. N., Kumar J. R., Reddy A. V., J. Chin Chem Soc. 54 (2007) 1233-1241.

Reddy K. J., Kumar J. R., Ramachandraiah C., Reddy A. V., Environ Monit Assess 136 (2008) 337-346.

Dakshinamoorthy A., Singh R. K., Iyer R. H., J Radioanal Nucl Chem. 177 (1994) 3 27-333.

Ruhela R., Sharma J. N., Tomar B. S., Panja S., Tripathi S. C., Hubli R. C., Suri A. K., Radiochim Acta 98 (2010) 209-214.

Jeffer G. H., Bassette J., Mendham J. A., Dennej R. C., Vogel Textbook of Quantitative Chemical Analysis, 5th edn, English Language Book Society, England (1984).

Singh A. K., Sharma S., Microchem J. 35 (1987) 365-368. (Received 14 November 2013; accepted 19 November 2013).

Show More Hide