Structural, Morphological and Optical Characterization of SnO2:F Thin Films Prepared by Chemical Spray Pyrolysis

Yousif, Salam Amir; Abass, Jenan Mohamed

doi:10.18052/www.scipress.com/ILCPA.18.90

ILCPA > ILCPA Volume 18 > Structural, Morphological and Optical...

< Back to Volume

Structural, Morphological and Optical Characterization of SnO₂:F Thin Films Prepared by Chemical Spray Pyrolysis

Full Text PDF

Abstract:

Fluorine doped tin oxide (FTO) films were successfully prepared on glass and quartz substrate at a substrate temperature equal to 450 °C for different fluorine doping (0, 0.05, 0.1, 0.15) by a homemade spray pyrolysis technique. The spray solution prepared from tin tetrachloride pentahydrate (SnCl_{4 · 5H2}O) dissolved in distilled water at (0.1 M) concentration and ammonium fluoride (NH₄F) was added into the solution for fluorine doping. X-ray diffraction patterns of the spray-deposited (SnO₂: F) films for different fluorine doping show that all the diffractograms contain the characteristic SnO2 orientations. The matching of the observed and standard d-values confirm that the deposited films are of tin oxide with tetragonal structure and the films are polycrystalline with (110) as a preferred growth orientation. The surface morphology of SnO₂: F thin film has been examined by atomic force microscopy (AFM). The average transmittance in the visible region (at 550 nm) has been found (40%, 47%, 52%, 59%, 61%) for the fluorine doping (0, 0.05, 0.1, 0.15, 0.2) respectively.

Info:

Periodical:

International Letters of Chemistry, Physics and Astronomy (Volume 18)

Pages:

90-102

DOI:

https://doi.org/10.18052/www.scipress.com/ILCPA.18.90

Citation:

S. A. Yousif and J. M. Abass, "Structural, Morphological and Optical Characterization of SnO₂:F Thin Films Prepared by Chemical Spray Pyrolysis", International Letters of Chemistry, Physics and Astronomy, Vol. 18, pp. 90-102, 2013

Online since:

September 2013

Authors:

Salam Amir Yousif, Jenan Mohamed Abass

Keywords:

Diffraction, Optical Characterization, SnO₂, SnO₂:F, X-Ray

Export:

RIS, BibTeX, Text

Distribution:

Open Access

This work is licensed under a
Creative Commons Attribution 4.0 International License

References:

E. Elangovan, K. Ramamurthi, Appl. Surf. Sci. 249 (2005) 183.

F. Atay, M. Demir, S. Kose, V. Bilgin, I. Akyuz, J. Optoelectron. Adv. M. 9(7) (2007) 2217.

J. Isidorsson, C.G. Granqvist, Sol. Energy. Mat. Sol. C 44 (1996) 375.

K.L. Chopra, S. Major, D.K. Pandya, Thin Solid Films 102 (1983) 1.

C.G. Granqvist, Handbook of Inorganic Electronic Materials, Elsevier Puplication, The Netherlands, (1995).

B. Stjerna, E. Olsson, C.G. Granqvist, J. Appl. Phys. 76 (1994) 3797.

V. Vasu, A. Subrahmanyam, Thin Solid Films 193-194 (1990) 973.

C. Li, B. Hua, Thin Solid Films 310 (1997) 238.

B. Thangaraju, Thin Solid Films 402 (2002) 71.

H. Kim, R.C.Y. Auyeung, A. Pique, Thin Solid Films 516 (2008) 5052.

Arturo I. Martinez, Dwight R. Acosta, Thin Solid Films 483 (2005) 107.

Houng-Lei Ma, Xiao-Tao Hao, J. Ma, Ying-Ge Yang, J. Huang, De-Heng Zhang, XianGang Xu, Appl. Surf. Sci. 191 (2002) 313.

A.V. Moholkar, S.M. Pawar, K.Y. Rajpure, C.H. Bhosale, Mater. Lett. 61 (2007) 3030.

Sung-Sik Chang, M.S. Jo, Ceram. Int. 33 (2007) 511.

Z.B. Zhou, R.Q. Cui, Q.J. Pang, Y.D. Wang, F.Y. Meng, T.T. Suna, Z.M. Dingb, X.B. Yu, Appl. Surf. Sci. 172 (2001) 245.

H. Kim, A. Pique, Appl. Phys. Lett. 84 (2004) 218.

S. R. Vishwakarma, J.P. Upadhyay, H.C. Prasad, Thin Solid Films 176 (1989) 99.

J.P. Upadhyay, S.R. Vishwakarma, H.C. Prasad, Thin Solid Films 167 (1988) 7.

P.K. Manoj, B. Joseph, V.K. Vaidyan, D.S.D. Amma, Ceram. Int. 33 (2007) 273.

S. Suporthina, M.R. De Guire, Thin Solid Films 371 (2000) 1.

H.L. Hartnagel, A.L. Dawar, A.K. Jain, C. Jagadish, Semiconducting Transparent Thin Films, Institute of Physics Publishing, Bristol, (1995).

Te-Hua Fang, Win-Jin Chang, Appl. Surf. Sci. 220 (2003) 175.

B.J. Lokhande, D. Uplane, Appl. Surf. Sci. 167 (200) 243.

D.R. Acosta, E.P. Zironi, E. Montoya, W. Estrada, Thin Solid Films 288 (1996) 1.

T. Schuler, M.A. Aegerter, Thin Solid Films 351 (1999) 125.

K. Kim T.G. Finstad, W.K. Chu, X.B. Cox, R,W. Linton, Solar Cells 13 (1984) 301.

S. Ghosh, H. Kim, K. Hang, C. Lee, Mater Sci. Eng., B, Solid-State Mater. Adv. Technol. 95 (2002) 171.

M. Okuya, J. Eur. Ceram. Soc. 21 (2001) (2099).

J.R. Brown, P.W. Haycock, L.M. Smith, A.C. Jones, E.W. Williams, Sens. Actuators B, Chem. 63 (2000) 109.

O.K. Varghese, L.K. Malhotra, J. Appl. Phys. 87 (2000) 7457.

Q. Chen, Y. Qian, Z. Chen, G. Zhou, Y. Zhang, Thin Solid Films 264 (1995) 25.

M. Kojima, H. Kato, M. Gatto, Pilos. Mag. B 68 (1993) 215.

H. Cachet, J. Bruneaux, G. Folcher, C. Levy-Clement, C. Vard, M. Neumann-Spallart, Sol. Energ. Mat. Sol. C. 46 (1997) 101.

I. Taniguchi, D. Song, M. Wakihara, J. Power Sources 109 (2002) 333.

P.S. Patil, Mater. Chem. Phys. 59 (1999) 185.

Powder Diffraction File Alphabetic PDF-2 Data Base, file41-1445, International center of Diffraction Data, Newtown Square, PA, USA, (1994).

D.W. Sheel, H.M. Yates, P. Evans, U. Dagkaldiran, A. Gordijn, F. Finger, Z. Remes, M. Vanecek, Thin Solid Films 517 (2009) 3061-3065.

A.A. Yadav, E.U. Masumdar, A.V. Moholkar, M. Neumann-Spallart, K.Y. Rajpure, C.H. Bhosale, J. Alloys Compd. 488 (2009) 350-355.

C. Barret, T.B. Massalski, Structure of Metals, Pergamon, Oxford, 1980, (923p).

T. Obata, K. Komeda, T. Nakao, H. Ueba, and C. Tasygama, J. Appl. Phys. 81 (1997) 199.

P. Šutta, Q. Jackuliak, Mater. Struct. 5(1) (1998) 10-14.

Saad F. Oboudi, Nadir F. Habubi, Ghuson H. Mohamed, Sami S. Chiad, International Letters of Chemistry, Physics and Astronomy 8(1) (2013) 78-86.

Sujan Kumar Das, Jahid M. M. Islam, Monirul Hasan, Humayun Kabir, Md. Abdul Gafur, Enamul Hoque, Mubarak A. Khan, International Letters of Chemistry, Physics and Astronomy 10(1) (2013) 90-101.

J. A. Najim, J. M. Rozaiq, International Letters of Chemistry, Physics and Astronomy 10(2) (2013) 137-150.

Majid H. Hassouni, Khudheir A. Mishjil, Sami S. Chiad, Nadir F. Habubi, International Letters of Chemistry, Physics and Astronomy 11 (2013) 26-37.

C. Indira Priyadharsini, A. Prakasam, P. M. Anbarasan, International Letters of Chemistry, Physics and Astronomy 12 (2013) 82-93 ( Received 27 August 2013; accepted 31 August 2013 ).

Show More Hide

Cited By:

[1] A. Omran Alkhayatt, S. Hussian, "Fluorine highly doped nanocrystalline SnO2 thin films prepared by SPD technique", Materials Letters, Vol. 155, p. 109, 2015

DOI: https://doi.org/10.1016/j.matlet.2015.04.130

[2] P. Pascariu, A. Airinei, N. Olaru, I. Petrila, V. Nica, L. Sacarescu, F. Tudorache, "Microstructure, electrical and humidity sensor properties of electrospun NiO–SnO2 nanofibers", Sensors and Actuators B: Chemical, Vol. 222, p. 1024, 2016

DOI: https://doi.org/10.1016/j.snb.2015.09.051

[3] D. Potter, D. Bhachu, M. Powell, J. Darr, I. Parkin, C. Carmalt, "Al-, Ga-, and In-doped ZnO thin films via aerosol assisted CVD for use as transparent conducting oxides", physica status solidi (a), Vol. 213, p. 1346, 2016

DOI: https://doi.org/10.1002/pssa.201532996

[4] M. Chitra, K. Uthayarani, N. Rajasekaran, N. Neelakandeswari, E. Girija, D. Padiyan, G. Mangamma, "Enhanced ethanol gas sensing performance of zinc–tin–vanadium oxide nanocomposites at room temperature", RSC Advances, Vol. 6, p. 111526, 2016

DOI: https://doi.org/10.1039/C6RA24047J

[5] G. Turgut, "Evaluation of Nd-Loaded SnO2:F Films Coated via Spray Pyrolysis", Journal of Electronic Materials, Vol. 47, p. 4149, 2018

DOI: https://doi.org/10.1007/s11664-018-6314-6

[6] R. Kisslinger, S. Riddell, S. Savela, P. Kar, U. Thakur, S. Zeng, K. Shankar, "Transparent nanoporous P-type NiO films grown directly on non-native substrates by anodization", Journal of Materials Science: Materials in Electronics, 2019

DOI: https://doi.org/10.1007/s10854-019-01480-0

[7] H. Miranda, S. Velumani, C. Pérez, J. Krause, F. D’ Souza, E. De Obaldía, E. Ching-Prado, "Effects of changes on temperature and fluorine concentration in the structural, optical and electrical properties of SnO2:F thin films", Journal of Materials Science: Materials in Electronics, 2019

DOI: https://doi.org/10.1007/s10854-019-01933-6

[8] R. Aljarrah, A. Aljawdah, "Concentration Effects on Characteristics of Gas Sensors Based on SnO₂:Sb₂O₃ Thin Films", Materials Science Forum, Vol. 1039, p. 416, 2021

DOI: https://doi.org/10.4028/www.scientific.net/MSF.1039.416

Show More Hide