Application of Nondestructive Radio Tracer Technique in Performance Evaluation of Anion Exchange Resins Duolite ARA-9366 and Duolite A-171

Singare, P.U.

doi:10.18052/www.scipress.com/ILCPA.18.63

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Application of Nondestructive Radio Tracer Technique in Performance Evaluation of Anion Exchange Resins Duolite ARA-9366 and Duolite A-171

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Abstract:

Radio analytical technique as a non-destructive technique was used in the present investigation to trace the kinetics of ion-isotopic exchange reaction taking place in Duolite ARA-9366 (nuclear grade) and Duolite A-171 (non-nuclear grade) anion exchange resins. The kinetics data suggest that during iodide ion-isotopic exchange reactions under identical experimental conditions of 40.00C, 1.000 g of ion exchange resins and 0.003 M labeled iodide ion solution, the values of specific reaction rate (min-1), amount of iodide ion exchanged (mmol), initial rate of iodide ion exchange (mmol/min) and log Kd were 0.176, 0.383, 0.067 and 7.8 respectively for Duolite ARA-9366 resin, which was higher than 0.142, 0.353, 0.050 and 7.0 respectively as that obtained for Duolite A-171 resins. Also it is observed that at a constant temperature of 40.0 °C, as the concentration of labeled iodide ion solution increases 0.001 M to 0.004 M, the percentage of iodide ions exchanged increases from 49.20% to 51.80% for Duolite ARA-9366 resins; and from 45.20% to 47.80% for Duolite A-171 resins. The similar trend was observed for the two resins during bromide ion-isotopic exchange reactions. The overall results indicate superior performance of Duolite ARA-9366 resins over Duolite A-171 resins under identical operational parameters.

Info:

Periodical:

International Letters of Chemistry, Physics and Astronomy (Volume 18)

Pages:

63-76

DOI:

https://doi.org/10.18052/www.scipress.com/ILCPA.18.63

Citation:

P.U. Singare, "Application of Nondestructive Radio Tracer Technique in Performance Evaluation of Anion Exchange Resins Duolite ARA-9366 and Duolite A-171", International Letters of Chemistry, Physics and Astronomy, Vol. 18, pp. 63-76, 2013

Online since:

September 2013

Authors:

P.U. Singare

Keywords:

¹³¹I, ⁸²Br, Duolite A-171, Duolite ARA-9366, Ion-Isotopic Exchange Reactions, Non-Destructive Tracer Technique, Nuclear Grade Resin, Radio Analytical Technique, Radioactive Tracer Isotopes, Reaction Kinetics

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References:

Samanta S. K., Ramaswamy M., Misra B. M., Sep. Sci. Technol. 27 (1992) 255-267.

Samanta S. K., Ramaswamy M., Sen P., Varadarajan N., Singh R. K., Removal of radiocesium from alkaline IL waste, Natl Symp. On Management of Radioactive and Toxic Wastes (SMART-93), Kalpakkam, 1993, Bhabha Atomic Research Centre, Bombay 1993, 56-58.

Samanta S. K., Theyyunni T. K., Misra B. M., J. Nucl. Sci. Technol. 32 (1995) 425-429.

Kulkarni Y., Samanta S. K., Bakre S. Y., Raj K., Kumra M. S., Process for treatment of intermediate level radioactive waste based on radionuclide separation, Waste Management'96 (Proc. Int. Symp Tucson, AZ, 1996), Arizona Board of Regents, Phoenix, AZ (1996).

Bray L. A., Elovich R. J., Carson K. J., Cesium Recovery using Savannah River Laboratory Resorcinol-formaldehyde Ion Exchange Resin, Rep. PNL- 7273, Pacific Northwest Lab., Richland, WA (1990).

Singare P. U., Lokhande R. S., Madyal R. S., Open Journal of Physical Chemistry 1(2) (2011) 45-54.

Singare P. U., Lokhande R. S., Madyal R. S., Rus. J. Gen. Chem. 80(3) (2010) 527-532.

Tomoi M., Yamaguchi K., Ando R., Kantake Y., Aosaki Y., Kubota H., J. Appl. Poly. Sci. 64(6) (1997) 1161-1167.

Zhu L., Liu Y., Chen J., Ind. Eng. Chem. Res. 48(7) (2009) 3261-3267.

Kumaresan R., Sabharwal K. N., Srinivasan T. G., Vasudeva Rao P. R., Dhekane G., Solvent Extraction and Ion Exchange 24(4) (2006) 589-602.

Cortina J. L., Warshawsky A., Kahana N., Kampel V., Sampaio C. H., Kautzman R. M., Reactive and Functional Polymers 54(1-3) (2003) 25-35.

Sood D. D., Reddy A. V. R., Ramamoorthy N., Indian Association of Nuclear Chemists and Allied Scientists January (2004) 289-297.

Clark M. W., Harrison J. J., Payne T. E., Journal of Colloid and Interface Science 356(2) (2011) 699-705.

Dagadu C. P. K., Akaho E. H. K., Danso K. A., Stegowski Z., Furman L., Applied Radiation and Isotopes 70(1) (2012) 156-161.

Koron N., Bratkic A., Ribeiro Guevara S., Vahcic M., Horvat M., Applied Radiation and Isotopes 70(1) (2012) 46-50.

Singare P. U., Lokhande, R. S., Ionics 18(4) (2012) 351-357.

Lokhande R. S., Singare P. U., Radiochim. Acta 95(03) (2007) 173-176.

Lokhande R. S., Singare P. U., Patil V. V., Radiochemistry 50(06) (2008) 638-641.

Lokhande R. S., Singare P. U., J. Porous Mater. 15(03) (2008) 253-258.

Lokhande R. S., Singare P. U., Dole M. H., J. Nuclear and Radiochemical Sciences 7(02) (2006) 29-32.

Heumann K. G., Baier, K., Chromatographia 15(11) (1982) 701-703.

Singare P. U., Lokhande R. S., Patil V. V., Prabhavalkar T. S., Tiwari S. R. D., European J. Chemistry 1(1) (2010) 47-49.

Adachi S., Mizuno T., Matsuno R., J. Chromatogr. A 708 (1995) 177-183.

Shuji, A., Takcshi, M., Ryuichi, M., Biosci. Biotechnol. Biochem. 60(2) (1996) 338-340.

Pravin U. Singare, International Letters of Chemistry, Physics and Astronomy 6 (2013) 1-5.

P. U. Singare, International Letters of Chemistry, Physics and Astronomy 12 (2013) 1-13.

P. U. Singare, International Letters of Chemistry, Physics and Astronomy 12 (2013) 14-27. ( Received 24 August 2013; accepted 30 August 2013 ).

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