Preheated Fly-Ash Catalyzed Cyclization of Chalcones: Synthesis of some Substituted Pyrazole-1-Carbothioamides and Spectral Correlations in 3-(3,4-Dichlorophenyl)-5-(Substituted Phenyl)-4,5-Dihydro-1H-Pyrazole-1-Carbothioamides

Thirunarayanan, Ganesamoorthy; Sekar, K.G.

doi:10.18052/www.scipress.com/ILCPA.15.18

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Preheated Fly-Ash Catalyzed Cyclization of Chalcones: Synthesis of some Substituted Pyrazole-1-Carbothioamides and Spectral Correlations in 3-(3,4-Dichlorophenyl)-5-(Substituted Phenyl)-4,5-Dihydro-1H-Pyrazole-1-Carbothioamides

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Abstract:

Some substituted 1-thiocarbomyl pyrazolines including 3-(3,4-dichlorophenyl)-5-(substituted phenyl)-4,5-dihydro-1H-pyrazole-1-carbothioamides using solvent-free preheated fly-ash catalyzed cyclization between chalcones and thiosemicarbazide microwave irradiation. The yields of these thiocarbomyl pyrazolines are more than 80%. The purities of these synthesised pyrazoline derivatives are checked by their physical constants and spectral data earlier reported in the literature. The spectral data of these 3-(3,4-dichlorophenyl)-5-(substituted phenyl)-4,5-dihydro-1H-pyrazole-1-carbothioamides had been correlated, using single and multi-linear regression analysis.

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Periodical:

International Letters of Chemistry, Physics and Astronomy (Volume 15)

Pages:

18-34

DOI:

https://doi.org/10.18052/www.scipress.com/ILCPA.15.18

Citation:

G. Thirunarayanan and K.G. Sekar, "Preheated Fly-Ash Catalyzed Cyclization of Chalcones: Synthesis of some Substituted Pyrazole-1-Carbothioamides and Spectral Correlations in 3-(3,4-Dichlorophenyl)-5-(Substituted Phenyl)-4,5-Dihydro-1H-Pyrazole-1-Carbothioamides", International Letters of Chemistry, Physics and Astronomy, Vol. 15, pp. 18-34, 2013

Online since:

June 2013

Authors:

Ganesamoorthy Thirunarayanan, K.G. Sekar

Keywords:

3-(3,4-Dichlorophenyl)-5-(Substituted Phenyl)-4,5-Dihydro-1H-Pyrazole-1-Carbothioamides, Hammett Correlations, Pre-Heated Fly-Ash, Solvent-Free Synthesis

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References:

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Cited By:

[1] G. Thirunarayanan, K. Sekar, "Solvent-free one-pot cyclization and acetylation of chalcones: Synthesis of some 1-acetyl pyrazoles and spectral correlations of 1-(3-(3,4-dimethylphenyl)-5-(substituted phenyl)-4,5-dihydro-1H-pyrazole-1-yl) ethanones", Journal of Saudi Chemical Society, Vol. 20, p. 661, 2016

DOI: https://doi.org/10.1016/j.jscs.2013.12.002

[2] G. Thirunarayanan, K. Sekar, "SiO2-H2SO4 catalysed, microwave-assisted cyclization cum acetylation of 2-propenones under solvent-free condition: Synthesis and spectral correlations of some 1-acetyl pyrazolines", Journal of Taibah University for Science, Vol. 8, p. 124, 2014

DOI: https://doi.org/10.1016/j.jtusci.2013.11.003