IR &amp; NMR Spectral Studies of some 7-Substituted 9H-Fluorenacyl Bromides: Assessment of Substituent Effects

Thirunarayanan, Ganesamoorthy

doi:10.18052/www.scipress.com/ILCPA.14.152

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IR & NMR Spectral Studies of some 7-Substituted 9H-Fluorenacyl Bromides: Assessment of Substituent Effects

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Abstract:

A series of some 2-bromo-1-(2-substituted 9H-fluorene-7-yl)ethanones have been prepared. The purities of these ethanones have been checked by their physical constants and spectroscopic data. The spectral group frequencies of these enones have been assigned and correlated with Hammett substituent constants, F and R parameters. From the results of statistical analyses, the effects of substituent have been discussed.

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Periodical:

International Letters of Chemistry, Physics and Astronomy (Volume 14)

Pages:

152-161

DOI:

https://doi.org/10.18052/www.scipress.com/ILCPA.14.152

Citation:

G. Thirunarayanan, "IR & NMR Spectral Studies of some 7-Substituted 9H-Fluorenacyl Bromides: Assessment of Substituent Effects", International Letters of Chemistry, Physics and Astronomy, Vol. 14, pp. 152-161, 2013

Online since:

May 2013

Authors:

Ganesamoorthy Thirunarayanan

Keywords:

9H-Fluorenacyl Bromides, Correlation Analysis, Hammett Substituent Constants, IR Spectra, NMR Spectra

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References:

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Cited By:

[1] G. Thirunarayanan, K. Sekar, "Synthesis of some substituted pyrazole-1-carbothioamides and spectral correlations in 3-(3,4-dibromophenyl)-5-(substituted phenyl)-4,5-dihydro-1H-pyrazole-1-carbothioamides", QScience Connect, p. 18, 2013

DOI: https://doi.org/10.5339/connect.2013.18