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International Letters of Chemistry, Physics and Astronomy
ILCPA Volume 13
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New Copolymerizable Photoinitiators for Radiation Curing of Acrylic PSA
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New Copolymerizable Photoinitiators for Radiation Curing of Acrylic PSA

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Abstract:

This article presents a new class of copolymerizable photoinitiators containing vinyloxycarbonyl groups, known such as organic carbonate or carbamate. Novel copolymerizable photoinitiators have been prepared through the reaction between vinyl chloroformate and hydroxyl groups containing photoreactive derivatives such as benzophenone-, acetophenone-, benzoine-and anthrachinone-derivatives. The main emphasis is given to the influence of this new class of unsaturated photoinitiators on UV-crosslinking process of acrylic pressure-sensitive adhesives (PSA). Moreover, the paper describes the influence of various parameters such as UV-initiated crosslinking time and concentration of unsaturated photoinitiators on relevant PSA properties like tack, peel adhesion and shear strength (cohesion).

Info:

Periodical:
International Letters of Chemistry, Physics and Astronomy (Volume 13)
Pages:
57-65
DOI:
https://doi.org/10.18052/www.scipress.com/ILCPA.13.57
Citation:
Z. Czech et al., "New Copolymerizable Photoinitiators for Radiation Curing of Acrylic PSA", International Letters of Chemistry, Physics and Astronomy, Vol. 13, pp. 57-65, 2013
Online since:
May 2013
Authors:
Zbigniew Czech, Dominika Sowa, Paulina Ragańska
Keywords:
Acrylics, Copolymerizable Photoinitiators, Peel Adhesion, Pressure-Sensitive Adhesives (PSA), Shear Strength, Tack, UV-Crosslinking
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Distribution:
Open Access

Creative Commons License
This work is licensed under a
Creative Commons Attribution 4.0 International License

References:

[1] Z. Czech, Crosslinking of Acrylic PSA, Publisher Szczecin University of Technology, (1999).

[2] E. Andrzejewska, Progress in Polymer Science 26 (2001) 605-665.

[3] W. Baeumer, M. Köhler, J. Ohngemach, Conference Proceedings Radcure 86, September 8-11, Baltimore, Maryland, USA (1986) 443-454.

[4] R. Milker, Z. Czech, Adhäsion 6 (1989) 20-25.

[5] Z. Czech, Polimery 4 (2002) 8-15.

[6] Z. Czech, W. Blum, F. Hermann, Patent WO 94/14853, (1993) Lohmann.

[7] G. Auchter, Adhäsion 1/2 (1993) 14-20.

[8] Z. Czech, A. Butwin, J. Kabatc, J. Świderska, L. Shao, Y. Bai, Polymer Bulletin 68 (2012) 441-452.

[9] Z. Czech, A. Butwin, J. Kabatc, J. Świderska, Polymer Bulletin 69 (2012) 71-80.

[10] Z. Czech, A. Kowalczyk, J. Kabatc, J. Świderska, European Polymer Journal 48 (2012) 1446-1454.

[11] Z. Czech, Patent DE 195 01 025 (1995) Lohmann.

[12] Zbigniew Czech, Agnieszka Kowalczyk, Dominika Sowa, International Letters of Chemistry, Physics and Astronomy 1 (2013) 63-69.

DOI: https://doi.org/10.18052/www.scipress.com/ilcpa.6.63

[13] Zbigniew Czech, Dominika Sowa, Jagoda Kowalska, International Letters of Chemistry, Physics and Astronomy 3 (2013) 21-28.

DOI: https://doi.org/10.18052/www.scipress.com/ilcpa.8.21
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