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Synthesis and Spectral Studies of some N-[(E)-Phenylmethylidene]benzenesulfonamides
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Synthesis and Spectral Studies of some N-[(E)-Phenylmethylidene]benzenesulfonamides

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Abstract:

A series of some N-[(E)-phenylmethylidene]benzenesulfonamide derivatives have been synthesised using solid SiO2-H3PO4 catalyst under solvent free conditions in microwave irradiation. The synthesised E-N-benzene sulfonilimines purities have been verified by their physical constants and spectroscopic data. The spectral frequencies are correlated with Hammett substituent constants, F and R parameters using linear regression analysis. From the results of statistical analysis the effect of substituents on the group frequencies will be discussed.

Info:

Periodical:
International Letters of Chemistry, Physics and Astronomy (Volume 13)
Pages:
249-258
DOI:
https://doi.org/10.18052/www.scipress.com/ILCPA.13.249
Citation:
K.G. Sekar and G. Thirunarayanan, "Synthesis and Spectral Studies of some N-[(E)-Phenylmethylidene]benzenesulfonamides", International Letters of Chemistry, Physics and Astronomy, Vol. 13, pp. 249-258, 2013
Online since:
May 2013
Authors:
K.G. Sekar, Ganesamoorthy Thirunarayanan
Keywords:
Greener Synthesis, Hammett Correlation, N-[(E)-Phenylmethylidene]benzenesulfonamides, SiO2-H3PO4
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Open Access

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