Paper Titles in Periodical
International Letters of Chemistry, Physics and Astronomy
Volume 12

Subscribe

Subscribe to our Newsletter and get informed about new publication regulary and special discounts for subscribers!

ILCPA > Volume 12 > Selective Separation of Cerium from Lanthanides by...
Selective Separation of Cerium from Lanthanides by Extractive Photometry Using HDBE as Novel Reagent
< Back to Volume

Selective Separation of Cerium from Lanthanides by Extractive Photometry Using HDBE as Novel Reagent

Full Text PDF

Abstract:

Striking similarities in properties of lanthanides make their separation a difficult task. Development of highly selective analytical reagent hexane-2,5-dione-bis(ethylenediamine) HDBE that forms brown coloured complex with Ce(IV) which is quantitatively extracted into xylene at pH 6.4. Transfer of extracted complex to organic phase is very fast (<1min.). Optimum concentration of reagent required for complexation and full colour development is very low (0.8 cm3 of 0.1 % HDBE). Absorption maximum exhibited at 518 nm. Beer’s law is obeyed in the detectable range 0.3-4.0 ppm. The molar absorptivity and Sandell’s sensitivity values are 0.421·104 dm3· mol-1·cm-1 and 0.017 µg·cm-2 respectively. The present method is time honoured, permits selective separation of cerium from associated lanthanones using HDBE as a novel complexing agent.

Info:

Periodical:
International Letters of Chemistry, Physics and Astronomy (Volume 12)
Pages:
144-150
DOI:
https://doi.org/10.18052/www.scipress.com/ILCPA.12.144
Citation:
Y. Bambardekar et al., "Selective Separation of Cerium from Lanthanides by Extractive Photometry Using HDBE as Novel Reagent", International Letters of Chemistry, Physics and Astronomy, Vol. 12, pp. 144-150, 2013
Online since:
Sep 2013
Authors:
Y. Bambardekar, Pravin U. Singare, R.S. Lokhande
Keywords:
Beer’s Law, Extracted Complex, HDBE, Lanthanides, Molar Absorptivity, Sandell Sensitivity, Xylene
Export:
RIS, BibTeX, Text
Distribution:
Open Access

Creative Commons License
This work is licensed under a
Creative Commons Attribution 4.0 International License

References:

[1] Sadanobu Inoue, Qiangbin Zhang, Masayuki Uto, Hirotsugu Minami, Solvent Extraction And Ion Exchange 22(4) (2004) 599-610.

DOI: https://doi.org/10.1081/sei-120038703

[2] A. Paulenova, M. Yu. Alyapyshev, Seventh International Conference on Nuclear and Radiochemistry, Budapest, Hungary (2008) Retrieved on5 th Jan. 2009 at www. nrc7. mke. org. nu.

[3] Chemjobber", Separating lanthanides-physical versus chemical methods, (December2010), available at www. chemistry-blog. com.

[4] Derek Brigham-Research article on Lanthanide Extraction Study, published in August 2010 available at http: /www. wsutoday. wsu. edu.

[5] Fariborz Riachi, Mojtaba-Research article on Separation of some lanthanide ions using 18-crowns-6 derivatives from acidic solutions Available at http: /scialert. net/abstract/?doi=Jas 2010, 1781-1786.

DOI: https://doi.org/10.3923/jas.2010.1781.1786

[6] Isabella Billard, Analytical and Bioanalytical Chemistry 400(6) (2011) 1555-1566.

[7] Nandkumar Deorkar, S. M. Khopkar, Analyst 114 (1989) 105-107.

[8] Souflame Mekki, Chien Wai, Chemistry (Weinheim ander Bergstrasse, Germany) 12(6), (2006) 1760-1766.

[9] Testsuya Uda, K. Thomas Jacob, M. Hirasawa, Science 289 (2000) 2326-2329.

[10] K. Veno, Organic Analytical Reagent, (1992), 2nd Ed. CRC press Boca Raton F. L. Material Science and Engg., Symposium (2007).

Show More Hide