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ILCPA > Volume 11 > Synthesis and Spectroscopic Characterization of...
Synthesis and Spectroscopic Characterization of <i>l</i>-Aspartic Acid Complexes with Metals of the Lanthanides Family
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Synthesis and Spectroscopic Characterization of l-Aspartic Acid Complexes with Metals of the Lanthanides Family

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Abstract:

The complexes between l-aspartic acid and metals of lanthanide series (La3+, Pr3+, Eu3+, Gd3+) have been prepared and characterized using a variety of techniques including, infrared spectroscopy, 1H NMR, 13C NMR, elemental analysis and metal contents. The sought metal effect on the electronic environment of the chiral carbon and its neighbouring atoms was observed in case of Europium and Praseodymium. The 13C downfield shift indicates a lower electron density at the carbon with consequent downfield shift observed on the α-H attached to it increasing its acidity.

Info:

Periodical:
International Letters of Chemistry, Physics and Astronomy (Volume 11)
Pages:
91-115
DOI:
https://doi.org/10.18052/www.scipress.com/ILCPA.11.91
Citation:
M. E. Mohamed "Synthesis and Spectroscopic Characterization of l-Aspartic Acid Complexes with Metals of the Lanthanides Family", International Letters of Chemistry, Physics and Astronomy, Vol. 11, pp. 91-115, 2013
Online since:
September 2013
Authors:
Musa E. Mohamed
Keywords:
IR, Lanthanides (III) Complexes, l-Aspartic Acid, NMR
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Distribution:
Open Access

Creative Commons License
This work is licensed under a
Creative Commons Attribution 4.0 International License

References:

Legendzewicz J., Huskowska E., Argay G. Y., Waskowska, A., J. Less-Common Met. 146 (1989) 33.

Benelli C., Caneschi A., Gatteschi D., Paradi N. A. L., Magnetic Molecular Materials 198 (1991) 233.

Ma B. Q., Zhang D. S., Gao S., Jin T. Z., Yan C. H., Xu G. X., Angew. Chem. Int. Ed. 39 (2000) 3644.

Ma A., Li L., Lin Y., Xi S., Jiegou Huaxue 14 (1995) 5.

Li X., Pan K., Jiegou Huaxue 4 (1985) 75.

Csoregh I., Kierkegaard P., Legendziewicz J., Huskowska E., Acta Chem. Scand. Sect. A 41 (1987) 453.

Torres J., Kremer C., Kremer E., Pardo H., Suescun L., Mombrú A., Domínguez S., Mederos, A., Herbst-Irmer, R., Arrieta, J. M., J. Chem. Soc., Dalton Trans. (2002) 4035.

Zheng H. D., Pan K. Z., Jiegou Huaxue 11 (1992) 393.

Wang J., Hu N., Yang K., Zhang H., Niu C., Acta Cryst. Sect. C 59 (2003) 52.

Csöregh I., Kierkegaard P., Legendziewicz J., Huskowska E., Acta Chem. Scand. 43 (1989) 636.

Wang R., Liu H., Carducci M. D., Jin T., Zheng C., Zheng Z., Inorg. Chem. 40 (2001) 2743-2750.

Celia R. C., Ana M. G. M., Segio R. D. E. L., J. Braz. Chem. Soc. 8(6) (1997) 597-602.

Wang R, Selby H. D., Liu H., Michael D. C., Jin T., Zheng Z., Anthis J. W., Staples R. J., Inorg. Chem. 41 (2002) 278-286.

Becker E.D., High resolution NMR-Theory and Chemical Applications, Academic Press, New York, (1980).

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